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投稿时间:2022-04-21 修订日期:2022-05-30 录用日期:2022-05-31 网络发布日期:2022-09-16
投稿时间:2022-04-21 修订日期:2022-05-30 录用日期:2022-05-31 网络发布日期:2022-09-16
中文摘要: 低温选择性催化还原(SCR)脱硝催化剂是目前烟气脱硝领域研究的热点。利用超声浸渍法制备了FeOx-CeOx-MnOx-TiO2/石墨烯低温SCR脱硝催化剂,研究和分析了FeOx添加量对催化剂脱硝性能的影响,并借助TEM、XPS分析探究了FeOx在催化剂中的作用及内在机制。结果表明,当Fe/Mn摩尔比为0.2时,催化剂具有最佳的脱硝效果,在140 ℃即具有90%的NO转化率;同时对催化剂的抗SO2和抗水性能进行了测定,表明FeOx的添加有利于其抗性的提升,在SO2和水共存的情况下,仍具有80%以上的NO转化率。在此基础上,通过对比SCR反应前后催化剂的FT-IR分析结果,剖析了可能的抗SO2抗水机理
Abstract:The catalysts for low temperature selective catalytic reduction (SCR) denitrification is the research hotpot in the field of flue gas denitrification. FeOx-CeOx-MnOx-TiO2/graphene catalysts for low temperature SCR denitrification were synthesized by ultrasonic impregnation. Effect of addition amount of FeOx on denitrification performance of the catalysts was studied, and the role and mechanism of FeOx in catalyst were investigated by TEM and XPS analysis. The results show that when Fe/Mn molar ratio is 0.2, the catalyst has the best denitrification performance. When the temperature is 140 ℃, NO conversion rate is as high as 90%. The resistance of catalysts to SO2 and H2O were also examined. The results show that addition of FeOx is beneficial to resistance of catalysts, and NO conversion is 80% above when SO2 and H2O exists together in the flue gas. On this basis, the possible mechanism of resistance for catalysts to SO2 and H2O are discussed by comparison of FT-IR results before and after denitrification reaction.
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基金项目:矿冶科技集团有限公司科研基金重点项目(02-1905)
| 作者 | 单位 | |
| 童震松* | 矿冶科技集团有限公司 | tongzhensong@163.com |
| 赵志龙 | 矿冶科技集团有限公司 | |
| 石培良 | 矿冶科技集团有限公司 |
| Author Name | Affiliation | |
| TONG Zhen-song | BGIMM Technology Group | tongzhensong@163.com |
| ZHAO Zhi-long | ||
| SHI Pei-liang |
引用文本:
童震松,赵志龙,石培良.添加FeOx对CeOx-MnOx-TiO2/石墨烯催化剂低温SCR脱硝性能的影响[J].有色金属(冶炼部分),2022(10):102-108.
TONG Zhen-song,ZHAO Zhi-long,SHI Pei-liang.Effect of FeOx Addition on Low Temperature SCR Denitrification Performance of CeOx-MnOx-TiO2/Graphene Catalysts[J].Nonferrous Metals (Extractive Metallurgy),2022(10):102-108.
童震松,赵志龙,石培良.添加FeOx对CeOx-MnOx-TiO2/石墨烯催化剂低温SCR脱硝性能的影响[J].有色金属(冶炼部分),2022(10):102-108.
TONG Zhen-song,ZHAO Zhi-long,SHI Pei-liang.Effect of FeOx Addition on Low Temperature SCR Denitrification Performance of CeOx-MnOx-TiO2/Graphene Catalysts[J].Nonferrous Metals (Extractive Metallurgy),2022(10):102-108.

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