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有色金属(冶炼部分):2022,(7):131-137
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不同钙源对MICP固化氰化尾渣的影响
王维大, 秦思远, 肖宇, 肖作义, 郑春丽
(内蒙古科技大学)
Effects of Different Calcium Sources on MICP Cured Cyanidation Tailings
WANG Wei-da, QIN Si-yuan, XIAO Yu, XIAO Zuo-yi, ZHENG Chun-li
(Inner Mongolia University of Science and Technology)
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投稿时间:2022-03-17     修订日期:2022-03-26     录用日期:2022-03-31     网络发布日期:2022-06-17
中文摘要: 为探究固化氰化尾渣最佳参数,实现最优试验方案,采用微生物诱导碳酸钙沉淀(MICP)技术,通过设计4种不同钙源,对比研究尿素与氯化钙、乙酸钙、硝酸钙和乳酸钙的4种胶结液,进行固化氰化尾渣,讨论了在不同钙源添加下MICP固化氰化尾渣的效果,分析了固化体无侧限抗压强度、重金属浸出和重金属形态、SEM和XRD表征等方法的可行性。物理力学指标表明,乙酸钙和氯化钙作为钙源时,固化氰化尾渣的效果优于硝酸钙和乳酸钙,结合SEM、FT-IR和XRD结果,确定乙酸钙为最优钙源。该研究可以为MICP技术在固化氰化尾渣工程应用提供科学依据和参考。
Abstract:In order to explore the best parameters of curing cyanidation tailings and realize the optimal test scheme, this thesis uses microbial induced calcium carbonate precipitation (MICP) technology, and through the design of four different calcium sources, to conduct the comparative study of calcium chloride, calcium acetate, calcium nitrate, calcium lactate and four kinds of cementing fluid of urea on curing cyanidation tailings. Effect of MICP curing cyanidation tailings with different calcium sources was discussed. The feasibility of unconfined compressive strength, heavy metal leaching and heavy metal morphology, SEM and XRD characterization were analyzed. Physical and mechanical indicators show that curing effect with calcium acetate and calcium chloride as calcium sources is better than that of with calcium nitrate and calcium lactate as calcium sources. Combined with SEM, FT-IR and XRD results, calcium acetate is the best calcium source. This study can provide scientific basis and reference for engineering application of MICP technology in curing cyanide tailings.
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基金项目:国家重点研发计划项目(2018YFC180017);国家自然科学基金资助项目(42167029);内蒙古自然科学基金面上基金资助项目(2020MS0547)
引用文本:
王维大,秦思远,肖宇,肖作义,郑春丽.不同钙源对MICP固化氰化尾渣的影响[J].有色金属(冶炼部分),2022(7):131-137.
WANG Wei-da,QIN Si-yuan,XIAO Yu,XIAO Zuo-yi,ZHENG Chun-li.Effects of Different Calcium Sources on MICP Cured Cyanidation Tailings[J].Nonferrous Metals (Extractive Metallurgy),2022(7):131-137.

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