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有色金属(冶炼部分):2020,(7):76-80
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锂电池LiFePO4正极材料性能改善方法综述
郑宇, 王杜, 刘勇奇, 巩勤学
(湖南邦普循环科技有限公司)
Summarization on Performance Improvement of LiFePO4 Cathode Materials for Lithium Ion Batteries
ZHENG Yu, WANG Du, LIU Yongqi, GONG Qinxue
(Hunan Brunp Recycling Technology Co.,Ltd.)
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投稿时间:2020-02-23     修订日期:2020-02-28     录用日期:2020-03-03     网络发布日期:2020-06-20
中文摘要: LiFePO4作为正极材料电化学性能优越,是发展潜力巨大的锂离子正极材料之一,但由于导电率和锂离子扩散速率问题,一直制约其发展。首先阐述了LiFePO4的微观结构、充放电原理以及充放电反应模型,回顾了近年来国内外改善磷酸铁锂的电化学性能所进行的研究,重点介绍了离子掺杂、碳包覆和材料纳米化方法对LiFePO4正极材料的影响以及目前仍然存在的问题,最后展望了该领域的发展趋势,并指出继续进行深入的理论研究和工艺改进是今后的重点研究方向。
中文关键词: 锂电池  正极材料  LiFePO4  综述
Abstract:Lithium iron phosphate cathode material is considered as one of the most promising cathode materials for lithium ion batteries due to its excellent electrochemical properties. However, its development is restricted by its low conductivity and slow diffusion rate of lithium ions. Crystal structure, charge-discharge principle and electrochemical reaction model of lithium iron phosphate are described. Recent studies on improving electrochemical performance of lithium iron phosphate at home and abroad are reviewed. Influence of modification methods such as ion doping, carbon coating and nano-materials on lithium iron phosphate cathode materials for lithium ion batteries and current existing problems are discussed. Finally, development trend in this field is prospected and the ideal that further theoretical research and process improvement is the key research direction in the future is put forward.
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基金项目:国家重点研发计划项目(2018YFC1901803)
引用文本:
郑宇,王杜,刘勇奇,巩勤学.锂电池LiFePO4正极材料性能改善方法综述[J].有色金属(冶炼部分),2020(7):76-80.
ZHENG Yu,WANG Du,LIU Yongqi,GONG Qinxue.Summarization on Performance Improvement of LiFePO4 Cathode Materials for Lithium Ion Batteries[J].Nonferrous Metals (Extractive Metallurgy),2020(7):76-80.

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