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投稿时间:2019-11-17 修订日期:2019-11-19 录用日期:2019-11-20 网络发布日期:2020-03-17
投稿时间:2019-11-17 修订日期:2019-11-19 录用日期:2019-11-20 网络发布日期:2020-03-17
中文摘要: 为研究钛含量对硅钛复合材料储锂性能的影响,将钛质量百分数含量分别为3.3%、6.4%和8%的硅钛复合物组装成锂离子电池负极并测试其电化学储锂能力。结果表明,钛的加入未改变活性物质硅的嵌/脱锂反应电位,但对负极的储锂能力影响显著。随着钛含量的增加,硅钛复合物的首次嵌锂比容量降低,首次库伦效率增大,当钛含量为8%时,负极的储锂能力最佳:首次嵌锂比容量为2 107.02 mAh/g,首次库伦效率为89.95%,经过经50圈循环后,容量保持率高达80.72%,平均衰减率仅有0.38%/圈。
Abstract:In order to investigate effect of titanium concentration on lithium-storage performance of silicon-titanium composite, silicon-titanium composite with titanium mass fraction of 3.3%, 6.4% and 8% was selected as anode of lithium-ion battery to investigate its electrochemical performance. The results suggest that addition of titanium is independent on lithiation/delithiation reaction potentials of active silicon, but affects lithium-storage performance of anode greatly. The first lithiation specific capacity of silicon-titanium composite drops and initial columbic efficiency of anode rises with increase of titanium concentration in silicon-titanium composite. When titanium concentration is 8%, lithiation-storage performance of anode reaches the best values with the first discharge specific capacity of 2 107.02 mAh/g and initial columbic efficiency of 89.95%. After cycling for 50 times, the specific capacity retention ratio of anode is 80.72% with average capacity decaying ratio of 0.38% per-cycle.
keywords: silicon-titanium anode titanium concentration lithiation-storage performance lithium-ion battery anode
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基金项目:国家自然科学基金资助项目(51804148);云南省应用基础研究计划项目(2018FD038)
引用文本:
张英杰,周忠仁,董鹏,张举峰,夏广辉,施晗程.钛含量对硅钛复合物储锂容量的影响[J].有色金属(冶炼部分),2020(4):71-74.
ZHANG Ying-jie,ZHOU Zhong-ren,DONG Peng,ZHANG Ju-feng,XIA Guang-hui,SHI Han-cheng.Influence of Titanium Concentration on Lithium-Storage Performance of Silicon-Titanium Composite[J].Nonferrous Metals (Extractive Metallurgy),2020(4):71-74.
张英杰,周忠仁,董鹏,张举峰,夏广辉,施晗程.钛含量对硅钛复合物储锂容量的影响[J].有色金属(冶炼部分),2020(4):71-74.
ZHANG Ying-jie,ZHOU Zhong-ren,DONG Peng,ZHANG Ju-feng,XIA Guang-hui,SHI Han-cheng.Influence of Titanium Concentration on Lithium-Storage Performance of Silicon-Titanium Composite[J].Nonferrous Metals (Extractive Metallurgy),2020(4):71-74.

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