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有色金属(冶炼部分):2017,(6):71-74
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基于生石灰强化处理的锰渣无害化技术
罗 乐,降林华,周 皓,段 宁
(重庆工程职业技术学院,中国环境科学研究院,重庆工程职业技术学院,中国环境科学研究院)
Harmless Treatment Technology of Manganese Slag Based on Quicklime
LUO Le,JIANG Lin-hua,ZHOU Hao and DUAN Ning
(Chongqing Vocational Institute of Engineering,Chongqing,,,)
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投稿时间:2017-02-12     修订日期:2017-02-15     录用日期:2017-02-16     网络发布日期:2017-05-19
中文摘要: 以酸浸锰渣为对象,生石灰为添加剂,翻转浸出法提取锰渣浸出液,分析了浸出液中的污染物类型及浓度,研究了生石灰添加量、锰渣含水率、预反应时间等对锰渣无害化处理的影响及最优条件。结果表明,锰渣中的主要污染物为锰和氨氮,且浓度严重超标。生石灰的水化反应形成了良好的碱性环境,以物理包裹、吸附及沉淀作用,起到了很好的无害化处理效果。最优的处理条件为:生石灰添加量10%、锰渣含水率27%、预搅拌时间40 min、预静置时间72 h,锰渣浸出液中可溶性锰浓度为2.60 mg/L,锰脱除率达99.8%,NH4 -N浓度为19.53 mg/L,脱除率为97.0%。
中文关键词: 生石灰  锰渣  无害化  可溶性锰  氨氮
Abstract:Manganese slag was leached by way of overturn with quicklime as additive. Types and concentration of pollutants in lixivium were analyzed. Effects of additive amount of quicklime, moisture content of manganese slag, and pre-reaction time on harmless treatment were analyzed. The results show that water-soluble Mn2 and NH4 -N are key pollutants with excessive concentration. Quicklime has hydration reaction with water to form good alkaline environment. Hydration reaction realizes good harmless treatment effect by physical inclusion, adsorption, and precipitation. Concentration of water-soluble Mn2 and NH4 -N is 2.60 mg/L and 19.53 mg/L respectively with removal ratio of manganese and NH4 -N of 99.8% and 97.0% respectively under the optimum conditions including additive amount of quicklime of 10%, moisture content of manganese slag of 27%, pre-mixing time of 40 min, and pre-reaction time of 72 h.
文章编号:     中图分类号:X757;X781.1    文献标志码:
基金项目:国家科技支撑计划项目(2012BAF03B03);国家水体污染控制与治理科技重大专项(2009ZX07529-005);科技部科研院所技术开发研究专项资金(2010EG166314)
引用文本:
罗 乐,降林华,周 皓,段 宁.基于生石灰强化处理的锰渣无害化技术[J].有色金属(冶炼部分),2017(6):71-74.
LUO Le,JIANG Lin-hua,ZHOU Hao,DUAN Ning.Harmless Treatment Technology of Manganese Slag Based on Quicklime[J].Nonferrous Metals (Extractive Metallurgy),2017(6):71-74.

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