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投稿时间:2013-02-24 修订日期:2013-02-26 录用日期:2013-02-27 网络发布日期:2013-08-22
投稿时间:2013-02-24 修订日期:2013-02-26 录用日期:2013-02-27 网络发布日期:2013-08-22
中文摘要: 介绍了从电子脚镀锡铜针中回收锡和铜的工艺研究及生产实践。采用常温碱性电解脱锡,电解液无须加热循环流动,控制电流密度200 A/m2、槽电压0.2~0.4 V,电解液含Sn 8~15 g/L、NaOH 60~120 g/L时,铜、锡的直收率分别达到99.7%和94.5%。脱锡铜针抛光处理后可以直接电解生产符合GB/T467-2010标准中Cu-CATH-1要求的阴极铜,电解条件:装填光亮铜针高出电解液面5 cm以上,电流密度200 A/m2,槽电压0.7 V,电解液含Cu 45~50 g/L、H2SO4 150~180 g/L。
Abstract:The technical study and plant practice of recovery of tin and copper from electronic foot tin plated copper needle were introduced. Tin was separated by alkaline electrolysis at room temperature without heating and electrolyte circulating. The recovery rate of copper and tin is 99.7% and 94.5% respectively under the conditions including current density of 200 A/m2, cell voltage of 0.2~0.4 V, electrolyte composition of Sn of 8~15 g/L and NaOH of 60~120 g/L. Cathode copper according with the requirements of Cu-CATH-1 brand under GB/T467-2010 standards is directly electrolyzed from polished de-tinning copper needle under the electrolysis conditions including copper needle being 5 cm higher than electrolytic liquid level, current density of 200 A/m2, cell voltage of 0.7 V, electrolyte composition of Cu of 45~50 g/L and H2SO4 of 150~180 g/L.
keywords: tin plated copper needle de-tinning with alkaline electrolysis electrolysis cathode copper recovery
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| 作者 | 单位 | |
| 陈亮* | 广东清远云铜有色金属有限公司 | liangcsuc@163.com |
| 王勇 | 广东清远云铜有色金属有限公司 | |
| 熊振坤 | 广东清远云铜有色金属有限公司 | |
| 陈斌 | 广东清远云铜有色金属有限公司 |
| Author Name | Affiliation | |
| CHEN Liang | Guangdong Qingyuan Yunnan Copper Nonferrous Metals Co.,Ltd | liangcsuc@163.com |
| WANG Yong | ||
| XIONG Zhen-kun | ||
| Chen Bin |
引用文本:
陈亮,王勇,熊振坤,陈斌.从电子脚镀锡铜针中回收锡和铜[J].有色金属(冶炼部分),2013(9):15-18.
CHEN Liang,WANG Yong,XIONG Zhen-kun,Chen Bin.Recovery of Tin and Copper from Electronic Foot Tin Plated Copper Needle[J].Nonferrous Metals (Extractive Metallurgy),2013(9):15-18.
陈亮,王勇,熊振坤,陈斌.从电子脚镀锡铜针中回收锡和铜[J].有色金属(冶炼部分),2013(9):15-18.
CHEN Liang,WANG Yong,XIONG Zhen-kun,Chen Bin.Recovery of Tin and Copper from Electronic Foot Tin Plated Copper Needle[J].Nonferrous Metals (Extractive Metallurgy),2013(9):15-18.

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