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投稿时间：2011-06-10 网络发布日期：2011-12-30
投稿时间：2011-06-10 网络发布日期：2011-12-30
中文摘要: 沉淀钼酸铵后的溶液含铁、硅较高，为了综合回收利用钼，采用N235萃取分离钼。对影响萃取分离钼的因素进行考察。结果表明，采用20%N235+10%仲辛醇+70%的煤油体系在下述最佳工艺条件下可以有效实现钼、硅、铁的分离，钼萃取率达到95.0%以上：萃取平衡时间3~5 min、酸浓度5~20 g/L、级数4~5级、相比O/A=1/2~1/4。
Abstract:In order to recycle molybdenum comprehensively, solvent extraction process for Mo separation from solution contained high concentration of Si and Fe in N235-kerosene system was investigated. The effecting factors on Mo extraction were discussed. The results show that over 95% extraction rate of Mo could be gained and effective separation of Mo, Fe and Si under the following optimum conditions using 20% N235+10% sec-octyl octanol +70% kerosene extraction system: equilibrium time of 3~5 min, acidity of 5~20 g/L, countercurrent extraction series of 4~5, phase ratio of O/A=1/2~1/4.
keywords: solution extraction N235 molybdenum iron silicon
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基金项目:
| Author Name | Affiliation |
| HE Xiao-cai, XIE Gang, LI Hui-re, YANG Da-jin, XU Qing-xin | Kunming Metallurgy Research Institute, Kunming 650031, China |
引用文本：
和晓才，谢刚，李怀仁，杨大锦，徐庆鑫.高铁、高硅溶液中萃取钼[J].有色金属（冶炼部分）,2012(1):16-19.
HE Xiao-cai, XIE Gang, LI Hui-re, YANG Da-jin, XU Qing-xin.Extraction Separating Mo2+ from Solution with High Si and Fe Containing[J].Nonferrous Metals (Extractive Metallurgy),2012(1):16-19.
和晓才，谢刚，李怀仁，杨大锦，徐庆鑫.高铁、高硅溶液中萃取钼[J].有色金属（冶炼部分）,2012(1):16-19.
HE Xiao-cai, XIE Gang, LI Hui-re, YANG Da-jin, XU Qing-xin.Extraction Separating Mo2+ from Solution with High Si and Fe Containing[J].Nonferrous Metals (Extractive Metallurgy),2012(1):16-19.
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