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投稿时间:2024-11-05 修订日期:2024-12-19 录用日期:2024-12-23 网络发布日期:2025-04-19
投稿时间:2024-11-05 修订日期:2024-12-19 录用日期:2024-12-23 网络发布日期:2025-04-19
中文摘要: 为综合回收某热液蚀变型黏土锂矿中的石英和锂,开展了选冶联合提锂试验。原矿矿物成分主要为长石、石英、绿泥石、白云母,含Li2O 0.214%。采用制砂—擦洗—脱泥—磁选—浮选工艺流程回收石英,获得产率为8.45%、SiO2品位为99.16%的石英精矿,以及产率为5.02%、SiO2品位为95.43%的石英次精矿,锂主要富集于泥质矿物、弱磁性矿物和浮选尾矿中。采用硫酸熟化—水浸工艺进行提锂,适宜的工艺条件为:酸矿比1.5︰1、熟化温度160 ℃、熟化时间4.0 h、酸浓度60%、水浸液固比2︰1、水浸时间1.0 h,在此条件下,泥质矿物、弱磁性矿物和浮选尾矿中锂的浸出率分别为98.40%、91.21%、83.75%,锂的综合浸出率为93.67%。
Abstract:A combined beneficiation and metallurgy test study on lithium extraction was carried out to comprehensively recover quartz and lithium from a hydrothermal alteration clay-type lithium ore. The main mineral components of the raw ore are feldspar, quartz, chlorite, and muscovite, containing 0.214% of Li2O. The process of sand making, scrubbing, desliming, magnetic separation and flotation was adopted to recover quartz, and a quartz concentrate with yield of 8.45% and SiO2 grade of 99.16%, as well as a quartz secondary concentrate with yield of 5.02% and SiO2 grade of 95.43% was obtained. Lithium is mainly enriched in argillaceous minerals, weakly magnetic minerals and flotation tailings. The sulfuric acid curing and water leaching process was used to extract lithium. The appropriate process conditions are as follows: the acid-to-ore ratio is 1.5︰1, the curing temperature is 160 ℃, the curing time is four hours, the acid concentration is 60%, the liquid-to-solid ratio of water leaching is 2︰1, and the water leaching time is one hour. Under these conditions, the leaching rate of lithium in argillaceous minerals, weakly magnetic minerals and flotation tailings is 98.40%, 91.21% and 83.75%, respectively, and the comprehensive leaching rate of lithium is 93.67%.
keywords: clay-type lithium ore quartz comprehensive utilization
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基金项目:安徽省地矿局地质科技项目(340000242432401900001);安徽省地质实验研究所科技项目(AHDS-2023K02)
| 作者 | 单位 | |
| 夏亮* | 安徽省地质实验研究所(国土资源部合肥矿产资源监督检测中心 | 502441448@qq.com |
| 杜淑华 | 安徽省地质实验研究所(国土资源部合肥矿产资源监督检测中心) | |
| 朱国庆 | 安徽省地质实验研究所(国土资源部合肥矿产资源监督检测中心) | |
| 余长军 | 安徽省地质实验研究所(国土资源部合肥矿产资源监督检测中心) | |
| 吴磊 | 安徽省地质实验研究所(国土资源部合肥矿产资源监督检测中心) |
引用文本:
夏亮,杜淑华,朱国庆,余长军,吴磊.某热液蚀变型黏土锂矿选冶联合提锂试验[J].有色金属(冶炼部分),2025(5):72-77.
XIA Liang,DU Shuhua,ZHU Guoqing,YU Changjun,WU Lei.Combined Beneficiation and Metallurgy Test for Lithium Extraction from Hydrothermal Alteration Clay Lithium Ore[J].Nonferrous Metals (Extractive Metallurgy),2025(5):72-77.
夏亮,杜淑华,朱国庆,余长军,吴磊.某热液蚀变型黏土锂矿选冶联合提锂试验[J].有色金属(冶炼部分),2025(5):72-77.
XIA Liang,DU Shuhua,ZHU Guoqing,YU Changjun,WU Lei.Combined Beneficiation and Metallurgy Test for Lithium Extraction from Hydrothermal Alteration Clay Lithium Ore[J].Nonferrous Metals (Extractive Metallurgy),2025(5):72-77.

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