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投稿时间:2024-06-18 修订日期:2024-08-01 录用日期:2024-08-02 网络发布日期:2025-02-18
投稿时间:2024-06-18 修订日期:2024-08-01 录用日期:2024-08-02 网络发布日期:2025-02-18
中文摘要: 通过室内酸法柱浸试验,对内蒙古哈达图铀矿石不同酸度条件下铀浸出特征和动力学机制进行了探讨,系统分析了铀矿石矿物成分与浸出过程中浸出液pH值、Eh值、铀浓度、浸出速率,液计、渣计浸出率及吨矿、吨铀耗酸量,在此基础上进行浸出动力学机制的拟合。研究结果表明,铀矿石碳酸盐含量(0.58 %)与粘土矿物含量(10.20 %)均满足酸浸工艺要求;平均铀浓度为33.13~47.27 mg·L-1、渣计浸出率93.06~95.43 %和吨铀酸耗为37.78~95.49 t·tU-1,符合酸法地浸可行性关键指标。10 g·L-1条件下铀矿石液计、渣计浸出率达到88.20 %、95.43 %,吨铀耗酸仅为37.78 t·tU-1,考虑到最佳浸出效益及经济成本,试验现场酸度宜为10 g·L-1。酸度大于10 g·L-1,柱浸时铀浸出动力学机制符合混合作用控制模型,小于等于10 g·L-1则符合化学反应控制模型。
Abstract:The characteristics and kinetic mechanism of uranium leaching from Hadatu uranium ore in Inner Mongolia under different acidity conditions were discussed through laboratory acid column leaching test. The mineral composition of uranium ore, the pH value, Eh value, uranium concentration, leaching rate, leaching rate by liquid meter and slag meter, and acid consumption of tons of ore and tons of uranium were systematically analyzed. On this basis, the kinetic mechanism of leaching was fitted. The results show that the carbonate content of uranium ore (0.58 %) and clay mineral content (10.20 %) meet the requirements of acid leaching process. The average uranium concentration is 33.13~47.27 mg·L-1, the leaching rate by slag is 93.06~95.43 % and the consumption of tons of uranic acid is 37.78~95.49 t·tU-1, which meet the key indexes of the feasibility of acid leaching. Under the condition of 10 g·L-1, the leaching rate of uranium ore by liquid meter and slag meter is 88.20 % and 95.43 %, and the acid consumption per ton of uranium is only 37.78 t·tU-1. Considering the best leaching benefit and economic cost, the acidity of the test site should be g·L-1. When the acidity is greater than 10 g·L-1, the leaching kinetics conforms to the mixing control model, while when the acidity is less than or equal to 10 g·L-1, the leaching kinetics conforms to the chemical reaction control model.
keywords: Hadatu uranium mine acid uranium leaching uranium leaching rate tons of uranium deplete acid dynamics
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基金项目:国家自然科学基金项目“酸法地浸采铀中铀矿储层孔隙与渗透性时空演化规律”(U1967207);东华理工大学放射性地质与勘探技术国防重点学科实验室开放基金项目(2022RGET14)。
| 作者 | 单位 | |
| 刘勇毅 | 东华理工大学 | liuyy20000901@163.com |
| 刘金辉* | 东华理工大学 水资源与环境工程学院 | liujh1961@163.com |
| 阳奕汉 | 中核内蒙古矿业有限公司 | |
| 王健 | 东华理工大学 水资源与环境工程学院 | |
| 周意如 | 中核内蒙古矿业有限公司 | |
| 韦妙 | 东华理工大学 水资源与环境工程学院 | 15078618669@163.com |
| 郑文娟 | 中核内蒙古矿业有限公司 |
引用文本:
刘勇毅,刘金辉,阳奕汉,王健,周意如,韦妙,郑文娟.内蒙古哈达图铀矿石酸法铀浸出及动力学特征[J].有色金属(冶炼部分),2025(2):217-228.
LIU Yongyi,LIU Jinhui,YANG Yihan,WANG Jian,ZHOU Yiru,WEI Miao,ZHENG Wenjuan.Leaching and Kinetics Characteristics of Uranium from Hadatu Uranium Ore in Inner Mongolia by Acid Method[J].Nonferrous Metals (Extractive Metallurgy),2025(2):217-228.
刘勇毅,刘金辉,阳奕汉,王健,周意如,韦妙,郑文娟.内蒙古哈达图铀矿石酸法铀浸出及动力学特征[J].有色金属(冶炼部分),2025(2):217-228.
LIU Yongyi,LIU Jinhui,YANG Yihan,WANG Jian,ZHOU Yiru,WEI Miao,ZHENG Wenjuan.Leaching and Kinetics Characteristics of Uranium from Hadatu Uranium Ore in Inner Mongolia by Acid Method[J].Nonferrous Metals (Extractive Metallurgy),2025(2):217-228.

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