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有色金属(冶炼部分):2024,(6):148-153
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铝工业CO2捕集剂开发及应用
赵伟1, 李国维1, 康泽双2, 曹瑞雪2, 韩玉柱1, 闫琨2
(1.包头铝业有限公司;2.中铝郑州有色金属研究院有限公司)
Development and Application of CO2 Collector in Aluminum Industry
ZHAO Wei1,2, LI Guowei1, KANG Zeshuang, CAO Ruixue, HAN Yuzhu, YAN Kun
(1.Baotou Aluminum Co,LTD,Nei Menggu Bao tou;2.Inner Mongolia University of Science Technology,Nei Menggu Bao tou)
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投稿时间:2024-03-12     修订日期:2024-03-18     录用日期:2024-03-21     网络发布日期:2024-05-01
中文摘要: 以伯胺和烯胺为原料,采用复合法制备高效复合型CO2捕集剂,通过FT-IR、离子分析初步判断捕集剂与CO2反应前后药剂变化。并通过优化工艺参数,明确最佳捕集剂浓度、反应温度、组分配比、烟气浓度。最佳工艺条件为:高效复合型捕集剂浓度30%、进气浓度20%、反应温度30 ℃,此时捕集效率达到99%以上,有效捕集时间达到300 min,高温再生后可实现捕集剂循环使用。
Abstract:An efficient CO2 composite collector was prepared by composite method using primary amine and enamine as raw materials, the changes of the reagent before and after the reaction of the collector with CO2 were preliminatively determined by FT-IR and ionic analysis. The optimum concentration, reaction temperature, composition ratio and flue gas concentration were determined by optimizing the process parameters. The capture efficiency is above 99% and the effective capture time is 300 min under the optimum conditions including the concentration of efficient composite collector of 30%, the intake concentration of 20%, and the reaction temperature of 30 ℃. The collector can be recycled after high temperature desorption.
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基金项目:内蒙古自治区科技计划项目(项目编号2022YFHH0150)
引用文本:
赵伟,李国维,康泽双,曹瑞雪,韩玉柱,闫琨.铝工业CO2捕集剂开发及应用[J].有色金属(冶炼部分),2024(6):148-153.
ZHAO Wei,LI Guowei,KANG Zeshuang,CAO Ruixue,HAN Yuzhu,YAN Kun.Development and Application of CO2 Collector in Aluminum Industry[J].Nonferrous Metals (Extractive Metallurgy),2024(6):148-153.

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