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投稿时间:2024-01-07 修订日期:2024-01-12 录用日期:2024-01-19 网络发布日期:2024-04-16
投稿时间:2024-01-07 修订日期:2024-01-12 录用日期:2024-01-19 网络发布日期:2024-04-16
中文摘要: 针对钒钛磁铁矿高炉冶炼副产的含钛高炉渣成分复杂、难以处理特点,采用氯化铵焙烧活化—浸出提质处理工艺,进行钙铝镁等杂质金属元素的脱除,获得钛富集物。考察焙烧和浸出过程中各参数对杂质脱除的影响。结果表明,在焙烧温度450 ℃、焙烧时间1 h、氯化铵配比40%、原料—0.074 mm占比83%,盐酸浓度9%、液固比5、浸出时间4 h、浸出温度90 ℃的优化条件下,含钛高炉渣中钙、铝、镁脱除率分别达到73.22%、90.04%、91.39%,钛损失率仅有0.34%,达到选择性脱除炉渣中杂质元素,提高含钛高炉渣品质的目的。
Abstract:Aiming at the characteristics of complex composition and difficult treatment of titanium-containing blast furnace slag of vanadium titanium-magnetite smelting byproduct, ammonium chloride roasting activation - leaching process was used to remove impurity metal elements such as calcium, aluminum and magnesium, to obtain titanium enrichment. The effects of various parameters on the removal of impurities during roasting and leaching were investigated. The results show that under the optimal conditions including roasting temperature of 450 ℃, roasting time of 1 h, ammonium chloride ratio of 40%, raw material of —0.074 mm accounts of 83%, hydrochloric acid concentration of 9%, liquid-solid ratio of 5, leaching time of 4 h, and leaching temperature of 90 ℃, the removal rate of calcium, aluminum and magnesium in titanium-bearing blast furnace slag is 73.22%, 90.04% and 91.39%, respectively, and the titanium loss rate is only 0.34%. This research achieves the purpose of selectively removing the impurity elements in the slag and improving the quality of titanium-containing blast-furnace slag.
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基金项目:矿冶科技集团有限公司科研基金项目(02-1944)
| 作者 | 单位 | |
| 谢思源 | 北京矿冶研究总院 | xies9527@dingtalk.com |
| 蒋伟* | 矿冶科技集团有限公司 | jwabar@126.com |
| 汪胜东 | 矿冶科技集团有限公司 | |
| 蒋训雄 | 矿冶科技集团有限公司 | |
| 张登高 | 矿冶科技集团有限公司 | |
| 毛寒成 | 矿冶科技集团有限公司 | |
| 赵峰 | 矿冶科技集团有限公司 |
引用文本:
谢思源,蒋伟,汪胜东,蒋训雄,张登高,毛寒成,赵峰.含钛高炉渣氯化铵焙烧活化试验[J].有色金属(冶炼部分),2024(5):68-75.
XIE Siyuan,JIANG Wei,WANG Shengdong,JIANG Xunxiong,ZHANG Denggao,MAO Hancheng,ZHAO Feng.Activation Test of Titanium-bearing Blast Furnace Slag by Roasting with Ammonium Chloride[J].Nonferrous Metals (Extractive Metallurgy),2024(5):68-75.
谢思源,蒋伟,汪胜东,蒋训雄,张登高,毛寒成,赵峰.含钛高炉渣氯化铵焙烧活化试验[J].有色金属(冶炼部分),2024(5):68-75.
XIE Siyuan,JIANG Wei,WANG Shengdong,JIANG Xunxiong,ZHANG Denggao,MAO Hancheng,ZHAO Feng.Activation Test of Titanium-bearing Blast Furnace Slag by Roasting with Ammonium Chloride[J].Nonferrous Metals (Extractive Metallurgy),2024(5):68-75.

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