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有色金属(冶炼部分):2024,(6):85-96
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加热温度对工业规模CeCl3喷雾焙烧反应器影响的数值模拟
董云芳1, 张松松1, 王振峰1, 伍永福1, 刘中兴1, 刘铃声2
(1.内蒙古科技大学;2.包头稀土研究院)
Numerical Simulation of Effect of Heating Temperature on Industrial Scale CeCl3 Spray Roasting Reactor
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投稿时间:2024-01-04     修订日期:2024-01-15     录用日期:2024-01-17     网络发布日期:2024-05-01
中文摘要: CeO2颗粒由于具有优异的性能,市场对CeO2颗粒的需求逐年增加。为探究使用在氧化铁颗粒工业化生产的Ruthner型喷淋焙烧反应器生产CeO2颗粒的可能性,结合单液滴失重试验,使用ANSYS Fluent软件,分别探究550、650、750和850 ℃四种不同加热温度对反应器的影响。单液滴失重试验表明,氯化铈和氯化铁、氯化亚铁的热解过程基本一致,使用该型反应器制备CeO2颗粒理论上可行。对小型工业反应器进行等比例建模,研究反应器内部化学反应的具体过程。结果表明550 ℃是最合适的温度,对工业生产具有一定指导意义。
Abstract:Due to the excellent performance of CeO2 particles, the market demand for CeO2 particles is increasing year by year. In order to explore the possibility of using the Ruthner type spray roasting reactor for industrial production of iron oxide particles to produce CeO2 particles, combined with the single drop weight loss experiment, ANSYS Fluent software was used to explore the effects of four different heating temperatures on the reactor at 550, 650, 750 and 850 ℃. The experiment of single drop weight loss shows that the pyrolysis process of cerium chloride is basically the same as that of ferric chloride and ferrous chloride, and it is theoretically feasible to prepare CeO2 particles with this type of reactor. The specific process of chemical reaction inside a small industrial reactor was studied by modeling it at equal scale. The results show that 550 ℃ is the most suitable temperature, which has certain guiding significance for industrial production.
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基金项目:国家自然科学基金资助项目(51964039);内蒙古自然科学基金资助项目(2022LHMS05004,2021GG0103);白云鄂博稀土资源研究与综合利用国家重点实验室开放基金资助项目(2021H2275)
引用文本:
董云芳,张松松,王振峰,伍永福,刘中兴,刘铃声.加热温度对工业规模CeCl3喷雾焙烧反应器影响的数值模拟[J].有色金属(冶炼部分),2024(6):85-96.
DONG Yunfang,ZHANG Songsong,WANG Zhenfeng,WU Yongfu,LIU Zhongxing,LIU Lingsheng.Numerical Simulation of Effect of Heating Temperature on Industrial Scale CeCl3 Spray Roasting Reactor[J].Nonferrous Metals (Extractive Metallurgy),2024(6):85-96.

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