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有色金属(冶炼部分):2024,(4):170-177
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新型缓释EDTA对土壤铅镉释放的影响
章绍康1, 王光辉2, 吴静琳3, 寇海群1, 朱洲1
(1.豫章师范学院;2.东华理工大学;3.宜春市万载生态环境局)
Effect of New Kind Sustained Release EDTA on Release of Pb and Cd from Soil
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投稿时间:2023-11-22     修订日期:2023-12-02     录用日期:2023-12-12     网络发布日期:2024-03-04
中文摘要: 利用羧甲基壳聚糖的环境友好性和成模性将其作为缓释载体,将EDTA和羧甲基壳聚糖按照1︰1的配比通过喷雾干燥器制备了的缓释EDTA。以缓释EDTA为研究对象,进行了表征分析、缓释动力学研究、土壤重金属静态活化特性和动态淋溶特性研究。结果表明:缓释EDTA包封率可达87.51%,在水中释放过程符合Higuchi模型,具有明显的缓释效果。缓释EDTA相比EDTA可以在提高土壤溶液中Pb、Cd离子浓度的同时有效控制Pb、Cd离子的突增,促使土壤溶液中的Pb、Cd离子保持适量浓度持续提升。动态淋溶结果表明,添加两种不同形式的EDTA会显著提升Pb、Cd的淋失量,但缓释EDTA处理能显著降低Pb、Cd的初始淋失量和淋失总量,其中Pb和Cd的淋失总量分别降低了19.5%和20.9%。
Abstract:Based on its environmental friendly and molding properties, carboxymethyl chitosan was used as sustained release carrier, the sustained release EDTA was prepared by spray dryer with EDTA and carboxymethyl chitosan in the ratio of 1:1. Using sustained release EDTA as objects to carry out characterization analysis, sustained release kinetics research, static activation characteristics and dynamic leaching characteristics of heavy metals in soil. The results show that the encapsulation rate of sustained release EDTA can reach 87.51%, and the release process in water conforms to the Higuchi model, and has obvious sustained-release effect. Compared with EDTA, sustained-release EDTA can effectively control the surge of Pb and Cd ions while increasing the concentration of Pb and Cd ions in soil solution, so as to keep the appropriate concentration of Pb and Cd ions in soil solution continuously increasing. The dynamic elution results show that adding two different forms of EDTA could significantly increase the leaching loss of Pb and Cd, but the sustained release EDTA treatment could significantly reduce the initial leaching loss and total leaching loss of Pb and Cd, in which the total leaching loss of Pb and Cd is reduced by 19.5% and 20.9%, respectively.
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基金项目:国家自然科学基金资助项目(41761069);江西省教育厅科技项目(GJJ213112)
引用文本:
章绍康,王光辉,吴静琳,寇海群,朱洲.新型缓释EDTA对土壤铅镉释放的影响[J].有色金属(冶炼部分),2024(4):170-177.
ZHANG Shaokang,WANG Guanghui,WU Jinglin,KOU Haiqun,ZHU Zhou.Effect of New Kind Sustained Release EDTA on Release of Pb and Cd from Soil[J].Nonferrous Metals (Extractive Metallurgy),2024(4):170-177.

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