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投稿时间:2023-10-05 修订日期:2023-10-13 录用日期:2023-10-19 网络发布日期:2023-12-29
投稿时间:2023-10-05 修订日期:2023-10-13 录用日期:2023-10-19 网络发布日期:2023-12-29
中文摘要: 为改善以往生物浸铀效率不高的缺陷,通过添加外源Fe2+及改变矿物粒径来提高生物对铀的浸出率。研究结果表明:外源Fe2+浓度分别为0、0.5、1.0和2.0 g/L时,铀浸出率分别为87.34%、88.27%、91.23%、89.13%,当浸出体系中Fe2+浓度为1.0 g/L时,铀矿石会产生部分溶解且表面粗糙孔隙明显,有利于铀的浸出,溶浸液中存在适量的Fe2+对生物浸铀的能力具有提升效果。另外,外源Fe2+对铀矿生物浸出符合固体产物层缩核模型,浸出过程主要受扩散控制。当粒径<- mm和-5 mm时铀浸出率分别为91.23%和83.70%,矿物粒径适当减小可增大颗粒比表面积,同样利于铀的浸出。
Abstract:In order to enhance uranium bioleaching efficiency, exogenous Fe2+ was added and mineral particle sizes was changed to improve the bioleaching rate of uranium. When the concentration of exogenous Fe2+ is 0, 0.5, 1.0 and 2.0 g/L, the uranium leaching rate is 87.34%, 88.27%, 91.23% and 89.13%, respectively. At 1.0 g/L Fe2+ concentration, uranium ore undergoes partial dissolution, revealing prominent rough pores on the surface, which is conducive to the leaching of uranium. The presence of an optimal amount of Fe2+ in leaching solution can improve the bioleaching capability for uranium. Moreover, the bioleaching of uranium ore with exogenous Fe2+ is consistent with the solid product layer shrinking core model, indicating that the leaching process is predominantly controlled by diffusion. When the particle sizes is -2 mm and -5 mm, the leaching rate of uranium is 91.23% and 83.70%, respectively. The specific surface area of mineral particles can be increased with the appropriate reduction of mineral particle size, which is also conducive to the leaching of uranium.
keywords: uranium bioleaching exogenous Fe2+ grain sizes
文章编号: 中图分类号: 文献标志码:
基金项目:国防基础科研计划资助项目(JCKY2019401D003)
| 作者 | 单位 | |
| 辛燕 | 东华理工大学核资源与环境国家重点实验室 | 1459081315@qq.com |
| 刘勇 | 东华理工大学核资源与环境国家重点实验室 | |
| 张益硕 | 东华理工大学核资源与环境国家重点实验室 | 1316305962@qq.com |
| 李龙祥 | 东华理工大学核资源与环境国家重点实验室 | 865739632@qq.com |
| 周仲魁 | 东华理工大学核资源与环境国家重点实验室 |
引用文本:
辛燕,刘勇,张益硕,李龙祥,周仲魁.外源Fe2+浓度及矿物粒径对生物浸铀的影响[J].有色金属(冶炼部分),2024(2):64-71.
XIN Yan,LIU Yong,ZHANG Yishuo,LI Longxiang,ZHOU Zhongkui.Effects of Exogenous Fe2+ Concentration and Mineral Particle Size on Uranium Bioleaching[J].Nonferrous Metals (Extractive Metallurgy),2024(2):64-71.
辛燕,刘勇,张益硕,李龙祥,周仲魁.外源Fe2+浓度及矿物粒径对生物浸铀的影响[J].有色金属(冶炼部分),2024(2):64-71.
XIN Yan,LIU Yong,ZHANG Yishuo,LI Longxiang,ZHOU Zhongkui.Effects of Exogenous Fe2+ Concentration and Mineral Particle Size on Uranium Bioleaching[J].Nonferrous Metals (Extractive Metallurgy),2024(2):64-71.

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