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有色金属(冶炼部分):2024,(2):64-71
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外源Fe2+浓度及矿物粒径对生物浸铀的影响
辛燕, 刘勇, 张益硕, 李龙祥, 周仲魁
(东华理工大学核资源与环境国家重点实验室)
Effects of Exogenous Fe2+ Concentration and Mineral Particle Size on Uranium Bioleaching
XIN Yan, LIU Yong, ZHANG Yishuo, LI Longxiang, ZHOU Zhongkui
(State Key Laboratory of Nuclear Resources and Environment,East China University of Technology)
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投稿时间:2023-10-05     修订日期:2023-10-13     录用日期:2023-10-19     网络发布日期:2023-12-29
中文摘要: 为改善以往生物浸铀效率不高的缺陷,通过添加外源Fe2+及改变矿物粒径来提高生物对铀的浸出率。研究结果表明:外源Fe2+浓度分别为0、0.5、1.0和2.0 g/L时,铀浸出率分别为87.34%、88.27%、91.23%、89.13%,当浸出体系中Fe2+浓度为1.0 g/L时,铀矿石会产生部分溶解且表面粗糙孔隙明显,有利于铀的浸出,溶浸液中存在适量的Fe2+对生物浸铀的能力具有提升效果。另外,外源Fe2+对铀矿生物浸出符合固体产物层缩核模型,浸出过程主要受扩散控制。当粒径<- mm和-5 mm时铀浸出率分别为91.23%和83.70%,矿物粒径适当减小可增大颗粒比表面积,同样利于铀的浸出。
中文关键词: 铀  生物浸出  外源Fe2+  粒径
Abstract:In order to enhance uranium bioleaching efficiency, exogenous Fe2+ was added and mineral particle sizes was changed to improve the bioleaching rate of uranium. When the concentration of exogenous Fe2+ is 0, 0.5, 1.0 and 2.0 g/L, the uranium leaching rate is 87.34%, 88.27%, 91.23% and 89.13%, respectively. At 1.0 g/L Fe2+ concentration, uranium ore undergoes partial dissolution, revealing prominent rough pores on the surface, which is conducive to the leaching of uranium. The presence of an optimal amount of Fe2+ in leaching solution can improve the bioleaching capability for uranium. Moreover, the bioleaching of uranium ore with exogenous Fe2+ is consistent with the solid product layer shrinking core model, indicating that the leaching process is predominantly controlled by diffusion. When the particle sizes is -2 mm and -5 mm, the leaching rate of uranium is 91.23% and 83.70%, respectively. The specific surface area of mineral particles can be increased with the appropriate reduction of mineral particle size, which is also conducive to the leaching of uranium.
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基金项目:国防基础科研计划资助项目(JCKY2019401D003)
引用文本:
辛燕,刘勇,张益硕,李龙祥,周仲魁.外源Fe2+浓度及矿物粒径对生物浸铀的影响[J].有色金属(冶炼部分),2024(2):64-71.
XIN Yan,LIU Yong,ZHANG Yishuo,LI Longxiang,ZHOU Zhongkui.Effects of Exogenous Fe2+ Concentration and Mineral Particle Size on Uranium Bioleaching[J].Nonferrous Metals (Extractive Metallurgy),2024(2):64-71.

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