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投稿时间:2023-09-07 修订日期:2023-09-14 录用日期:2023-09-18 网络发布日期:2023-11-30
投稿时间:2023-09-07 修订日期:2023-09-14 录用日期:2023-09-18 网络发布日期:2023-11-30
中文摘要: 选取固体废物粉煤灰作为支撑体骨料,TiO2为烧结助剂,羧甲基纤维素(CMC)为黏结剂,木炭粉为造孔剂,采用固态粒子烧结法制得初始陶瓷膜支撑体样品,并对其进行等比尺寸(直径)放大制备。探究支撑体尺寸放大制备中烧结温度、造孔剂添加量、尺寸(直径)放大倍数等因素对支撑体性能的影响,对物质组成、微观形貌、抗折强度、纯水通量、酸碱腐蚀率及孔径分布等性能进行表征。结果表明:最高烧结温度为1 050 ℃,造孔剂木炭粉添加量为15%(质量分数),放大到原尺寸(直径)的2倍时,所制得支撑体性能最佳,其内部孔隙均匀,颈型结构明显,纯水通量为4 728.26 L/(m2?h?MPa),抗折强度为25.15 MPa,中值孔径为3.06 μm,孔隙率为38.56%,酸、碱质量损失率分别为0.33%、0.25%。
Abstract:Using solid waste fly ash as the supporting aggregate, TiO2 as the sintering agent, carboxymethyl cellulose (CMC) as the bonding agent, and charcoal powder as the pore making agent, the initial ceramic film supporting sample was prepared by solid particle sintering method, and the size (diameter) of the sample was amplified. The effects of sintering temperature, pore forming agent addition amount, size (diameter) amplification ratio and other factors on the performance of the support were investigated in the preparation of the support size scaling, and the material composition, micro-morphology, bending strength, pure water flux, acid-base corrosion rate and pore size distribution were characterized. The results show that, when the highest sintering temperature is 1 050 ℃, the addition amount of pore making agent charcoal powder is 15% (mass fraction), and the support body is enlarged to twice the original size (diameter), the performance of the prepared support body is the best. The internal pores are uniform, the neck structure is obvious, and the pure water flux is 4728.26 L/(m2?h?MPa), the bending strength is 25.15 MPa, the median pore size is 3.06 μm, the porosity is 38.56%, and the mass loss rate acid and alkali is 0.33% and 0.25% respectively.
文章编号: 中图分类号: 文献标志码:
基金项目:陕西省科技厅重点研发计划项目(2020GY-325,2020ZDLNY06-09,2020SF-410)
| 作者 | 单位 | |
| 常华 | 西安工程大学 环境与化学工程学院 | 576383419@qq.com |
| 詹辉 | 西安工程大学 环境与化学工程学院 | 2687603564@qq.com |
| 同帜* | 西安工程大学 环境与化学工程学院 | 1018915428@qq.com |
| 郭雅妮 | 西安工程大学 环境与化学工程学院 | |
| 杨万波 | 西安工程大学 环境与化学工程学院 |
引用文本:
常华,詹辉,同帜,郭雅妮,杨万波.粉煤灰基陶瓷膜支撑体的制备与尺寸放大试验[J].有色金属(冶炼部分),2024(1):80-90.
ChANG Hua,ZHAN Hui,TONG Zhi,GUO Yani,YANG Wanbo.Preparation and Size Scale-up Test of Ceramic Membrane Supports Based on Fly Ash[J].Nonferrous Metals (Extractive Metallurgy),2024(1):80-90.
常华,詹辉,同帜,郭雅妮,杨万波.粉煤灰基陶瓷膜支撑体的制备与尺寸放大试验[J].有色金属(冶炼部分),2024(1):80-90.
ChANG Hua,ZHAN Hui,TONG Zhi,GUO Yani,YANG Wanbo.Preparation and Size Scale-up Test of Ceramic Membrane Supports Based on Fly Ash[J].Nonferrous Metals (Extractive Metallurgy),2024(1):80-90.

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