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投稿时间:2023-06-19 修订日期:2023-07-06 录用日期:2023-07-07 网络发布日期:2023-10-09
投稿时间:2023-06-19 修订日期:2023-07-06 录用日期:2023-07-07 网络发布日期:2023-10-09
中文摘要: 以滇东北某冶炼企业地块作为研究区,根据污染源分布情况共布设37个采样点钻孔,在不同地层及深度采集了115件土壤样品,根据钻孔信息利用地层建模-钻孔模型方法建立了研究区三维地层模型,并根据土壤样品重金属浓度分析测试结果,对土壤中重金属的空间分布特征进行了分析,同时获取了不同重金属指标之间的浓度相关性,采用克里格插值数值模拟方法,建立了研究区土壤不同深度的重金属浓度分布模型,并对重金属的迁移特征及影响因素进行了分析。结果表明:1)受人类生产活动影响,表层土壤中重金属出现明显的累积效应,5种重金属的平均浓度远超背景值;水渣池区域As、Co超过了建设用地土壤污染风险第二类用地管控值,Cd、Ni、Pb超过了建设用地土壤污染风险第二类用地筛选值,出现了明显的污染现象。2)表层土壤中Co、Ni、Cd、As、Pb变异系数逐渐减小,表明浓度分布不均匀性受外源影响程度依次降低;变异系数随深度增加逐渐减小,表明人为生产活动等外源因素导致了浓度垂向分布不均匀,且随着深度的增加受外源影响程度逐渐减弱。3)As、Co、Ni显示出极显著相关,呈现出明显的相互伴生聚集现象,物质来源及受外源影响的作用极度相似;As-Cd、As-Pb、Co-Pb、Pb-Ni显示出较高相关性,相互聚集现象不明显;其他污染物之间的相关性较差,基本没有出现聚集现象。4)重金属在人工填土层范围内的垂向迁移特征明显,受下伏分布连续的第四系黏土层阻隔影响,随着深度的增加污染羽的弥散范围逐渐扩大;非饱和带中由于缺乏水动力作用,污染羽水平迁移迁移扩散作用不明显。
Abstract:Taking a metallurgical enterprise site in Northeast Yunnan as the research area, a total of 37 sampling site boreholes were laid out according to the distribution of pollution sources. In the 115 soil samples collected at different strata and depths, based on drilling information, formation modeling-drilling model in the research area, and according to the test results of heavy metal concentration analysis in soil samples, the spatial distribution of heavy metals in soil was analyzed. The concentration correlation between different heavy metal indicators was also obtained. Using the Kriging interpolation method, a heavy metal concentration distribution model for different depths of the soil in the study area was established. The migration characteristics and influencing factors of heavy metals were also analyzed. The results show that: 1) Affected by human production activities, the average concentration of five kinds of heavy metals far exceeds the background value; As and Co exceed the soil pollution risk control value of construction land, Cd, Ni and Pb exceed the screening value of the soil pollution risk of construction land, and the obvious pollution phenomenon appears. 2) The variation coefficient of Co, Ni, Cd, As, and Pb in surface soil gradually decreases, indicating that the uneven concentration distribution decreases successively; The variation coefficient gradually decreases with the increase of depth, indicating that exogenous factors such as artificial production activities lead to the uneven vertical distribution, and the exogenous influence degree of concentration gradually decreases with the increase of depth. 3) As, Co and Ni shows very significant correlation, showing obvious mutual aggregation phenomenon, extremely similar material source and exogenous influence; As-Cd, As-Pb, Co-Pb and Pb-Ni show high correlation, not obvious; The correlation between other pollutants is poor, and basically no aggregation phenomenon. 4) The vertical migration characteristics of heavy metals in the area of artificial filling layer are obvious, influenced by the barrier of quaternary clay layer, the horizontal migration and diffusion effect of the contaminated layer is not obvious.
文章编号: 中图分类号: 文献标志码:
基金项目:云南省省级党群系统决策咨询研究课题(ZD202000120A)
| 作者 | 单位 | |
| 董志芬 | 云南绿色环境科技开发有限公司 | 244216781@qq.com |
| 梁策 | 云南省核工业二〇九地质大队 云南省核工业二〇九地质大队 | |
| 谢容生* | 云南新世纪环境保护科学研究院 | xiers1990@163.com |
| 钟敏 | 云南绿色环境科技开发有限公司 |
引用文本:
董志芬,梁策,谢容生,钟敏.有色冶炼场地非饱和带重金属分布迁移特征及影响因素[J].有色金属(冶炼部分),2023(11):135-143.
DONG Zhifen,LIANG Ce,XIE Rongsheng,ZHONG Min.Distribution and Migration Characteristics and Influencing Factors of Heavy Metals in Unsaturated Zone of Metallurgical Enterprise Site[J].Nonferrous Metals (Extractive Metallurgy),2023(11):135-143.
董志芬,梁策,谢容生,钟敏.有色冶炼场地非饱和带重金属分布迁移特征及影响因素[J].有色金属(冶炼部分),2023(11):135-143.
DONG Zhifen,LIANG Ce,XIE Rongsheng,ZHONG Min.Distribution and Migration Characteristics and Influencing Factors of Heavy Metals in Unsaturated Zone of Metallurgical Enterprise Site[J].Nonferrous Metals (Extractive Metallurgy),2023(11):135-143.

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