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投稿时间:2023-05-16 修订日期:2023-05-25 录用日期:2023-05-29 网络发布日期:2023-09-04
投稿时间:2023-05-16 修订日期:2023-05-25 录用日期:2023-05-29 网络发布日期:2023-09-04
中文摘要: 以粒径—48 μm零价铁粉作为参照物,对比研究Fe78Si9B13非晶条带对水中Cr(Ⅵ)的去除效果。结果显示,非晶条带的去除过程满足伪一级动力学模型。反应25 min后,零价铁粉的Cr(Ⅵ)去除率仅为88%,非晶条带的去除率可达99.8%。对试验后反应产物进行观察分析,发现零价铁粉仅通过吸附去除Cr(Ⅵ),而非晶合金条带去除Cr(Ⅵ)的过程不仅有物理吸附,也发生了化学还原。
Abstract:The removal effect of Cr(Ⅵ) in water by Fe78Si9B13 amorphous ribbons was compared with zero-valent iron powder with particle size of —48 μm. The results show that the removal process of amorphous ribbons meets the pseudo-first-order dynamic model. After 25 minutes of reaction, the removal rate of zero-valent iron powders is only 88%, while the removal rate of amorphous ribbons is 99.8%. Through observation and analysis of the reaction products after the test, it is found that Cr(Ⅵ) is only removed by zero-valent iron powder through adsorption, while Cr(Ⅵ) is removed by amorphous alloy strip not only by physical adsorption, but also by chemical reduction.
keywords: Fe-based amorphous alloy Cr(Ⅵ) reduction adsorption
文章编号: 中图分类号: 文献标志码:
基金项目:国家自然科学基金资助项目(52061024,52161027);甘肃省自然科学基金资助项目(21JR7RA260);兰州理工大学红柳优秀青年人才支持计划项目
| 作者 | 单位 | |
| 张香云 | 兰州理工大学材料学院 | zhangxiangyun86@163.com |
| 赵晨凯* | 兰州理工大学材料学院 | 631198038@qq.com |
| 袁明强 | 兰州理工大学材料学院 | |
| 袁子洲 | 兰州理工大学材料学院 |
引用文本:
张香云,赵晨凯,袁明强,袁子洲.Fe78Si9B13非晶合金对水中Cr(Ⅵ)的去除性能研究[J].有色金属(冶炼部分),2023(10):120-125.
ZHANG Xiangyun,ZHAO Chenkai,YUAN Mingqiang,YUAN Zizhou.Study on Removal Performance of Cr(Ⅵ) in Water by Fe78Si9B13 Amorphous Alloy[J].Nonferrous Metals (Extractive Metallurgy),2023(10):120-125.
张香云,赵晨凯,袁明强,袁子洲.Fe78Si9B13非晶合金对水中Cr(Ⅵ)的去除性能研究[J].有色金属(冶炼部分),2023(10):120-125.
ZHANG Xiangyun,ZHAO Chenkai,YUAN Mingqiang,YUAN Zizhou.Study on Removal Performance of Cr(Ⅵ) in Water by Fe78Si9B13 Amorphous Alloy[J].Nonferrous Metals (Extractive Metallurgy),2023(10):120-125.

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