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投稿时间:2023-04-24 修订日期:2023-04-26 录用日期:2023-04-28 网络发布日期:2023-05-19
投稿时间:2023-04-24 修订日期:2023-04-26 录用日期:2023-04-28 网络发布日期:2023-05-19
中文摘要: 为减少高电流密度铜电解过程中阴极积瘤现象、降低残极率以及提高电流效率,本文基于多物理场耦合理论与正交实验方法,研究了进液管半径、阳极板底部圆角半径以及极间距对铜电解精炼效果的影响。单因素分析发现,随着进液管半径的增大或阳极圆角半径的增大,电流效率和阴极铜沉积厚度均匀性均呈现先增大后减小的趋势;随着极间距的增大,电流效率逐渐减小,阴极铜沉积厚度逐渐均匀。进行正交实验分析出使铜电解精炼效果优异的电解槽结构参数为:进液管半径3.5 mm,阳极底部圆角4 mm,极间距110 mm。本文为优化电解槽提高生产效率的研究提供理论指导。
Abstract:In order to reduce the phenomenon of cathode nodules in the electrolytic process of high current density copper, reduce the residual rate and improve the current efficiency. Based on multiple physical field coupling theory and orthogonal experiment method, the influences of inlet tube radius, anode bottom fillet radius and electrode spacing on electrolytic refining of copper were studied. Single factor analysis shows that the current efficiency and copper deposition uniformity increase first and then decrease with the increase of inlet pipe radius or anode fillet radius. With the increase of electrode spacing, the current efficiency decreases and the thickness of copper deposition becomes uniform. The structure parameters of the electrolytic cell with excellent copper electrolytic refining effect were analyzed by orthogonal experiment as follows: inlet tube radius 3.5mm, anode bottom fillet 4 mm, pole spacing 110 mm. This paper provides theoretical guidance for improving the production efficiency of electrolytic cell.
keywords: Copper electrolytic cell Anodic corrosion Numerical simulation Current efficiency uniformity
文章编号: 中图分类号: 文献标志码:
基金项目:国家自然科学基金项目(面上项目,重点项目,重大项目),工业含水锡粒微波干燥行为研究
| 作者 | 单位 | |
| 尚小标* | 昆明理工大学机电工程学院 | 18653717151@163.com |
| 张志浩 | 昆明理工大学机电工程学院 | 1515406942@qq.com |
| 肖人友 | 昆明理工大学机电工程学院 | 947611285@qq.com |
| 姚坤 | 昆明理工大学机电工程学院 | 1710850627@qq.com |
| 李佳剑 | 昆明理工大学机电工程学院 | 1749309974@qq.com |
引用文本:
尚小标,张志浩,肖人友,姚坤,李佳剑.基于正交实验的高电流密度铜电解槽结构优化[J].有色金属(冶炼部分),2023(6):153-161.
SHANG Xiao-biao,ZHANG Zhi-hao,XIAO Ren-you,YAO Kun,LI Jia-jian.Anodic corrosion uniformity of copper electrolysis cell based on multi-physical field coupling[J].Nonferrous Metals (Extractive Metallurgy),2023(6):153-161.
尚小标,张志浩,肖人友,姚坤,李佳剑.基于正交实验的高电流密度铜电解槽结构优化[J].有色金属(冶炼部分),2023(6):153-161.
SHANG Xiao-biao,ZHANG Zhi-hao,XIAO Ren-you,YAO Kun,LI Jia-jian.Anodic corrosion uniformity of copper electrolysis cell based on multi-physical field coupling[J].Nonferrous Metals (Extractive Metallurgy),2023(6):153-161.

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