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有色金属(冶炼部分):2023,(7):15-21
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超声强化含锌尘泥浸出机理及动力学
牛福生, 卜梓恒, 张晋霞, 何胜韬, 常朕嘉
(华北理工大学矿业工程学院)
Mechanisms and Kinetics of Ultrasonic Enhanced Leaching of Zinc-containing Dust
NIU Fu-sheng, BU Zi-heng, ZHANG Jin-xia, HE Sheng-tao, CHANG Zhen-jia
(College of Mining Engineering, North China University of Science and Technology)
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投稿时间:2023-03-15     修订日期:2023-03-22     录用日期:2023-03-27     网络发布日期:2023-06-16
中文摘要: 采用低共熔溶剂为浸出剂,进行从含锌尘泥超声浸锌试验。分析了超声功率、温度、液固比、搅拌速率、反应时间等对锌浸出率的影响。结果表明:在超声功率90 W、温度40 ℃、液固比7 mL/g、转速250 r/min、浸出时间80 min条件下,锌超声浸出率可达98.48%。超声强化浸出过程受混合固体产物层的控制,表观活化能为11.23 kJ/mol。
中文关键词: 冶金尘泥  锌  超声强化  动力学
Abstract:In this study, a deep eutectic solvent was used as the leaching agent in a pilot study on the ultrasonic leaching of zinc from zinc-containing dust sludge. The impact of ultrasonic power, reaction time, solid-liquid ratio, temperature, and stirring rate was examined on the zinc leaching rate. The results showed that under the conditions of temperature 40°C, ultrasonic power 90 W, solid-liquid ratio 1:7, rotating speed 250 r/min, and leaching time 80 min, the ultrasonic leaching rate of zinc could reach 98.5%. Based on the leaching results, the kinetic equation of ultrasound-enhanced leaching was developed. In the kinetic analysis of ultrasonically enhanced leaching of Zn-containing dust sludge, the apparent activation energy of the reaction was 11.2 kJ/mol, indicating that the mixed solid product layer controls the ultrasonically enhanced leaching process.
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基金项目:河北省自然科学基金资助项目(E2021209015);河北省教育厅重点项目(ZD2022059);河北省三三三人才项目(B20221005)
引用文本:
牛福生,卜梓恒,张晋霞,何胜韬,常朕嘉.超声强化含锌尘泥浸出机理及动力学[J].有色金属(冶炼部分),2023(7):15-21.
NIU Fu-sheng,BU Zi-heng,ZHANG Jin-xia,HE Sheng-tao,CHANG Zhen-jia.Mechanisms and Kinetics of Ultrasonic Enhanced Leaching of Zinc-containing Dust[J].Nonferrous Metals (Extractive Metallurgy),2023(7):15-21.

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