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有色金属(冶炼部分):2023,(3):111-117
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铥改性MnCeOx/TiO2催化剂在氨中低温还原NOx的优越性能
刘康, 魏博, 王珊, 王建江, 陈丽娟
(省部共建碳基能源资源化学与利用国家重点实验室)
Superior Performance of Thulium-Modified MnCeOx/TiO2 Catalysts for NOx Reduction at Low Temperature in Ammonia
LIU Kang, WEI Bo, WANG Shan, WANG Jian-jiang, CHEN Li-juan
(State Key Laboratory of Carbon-based Energy Resource Chemistry and Utilization,College of Chemical Engineering,Xinjiang University,Xinjiang Key Laboratory of Clean Coal Conversion and Chemical Process)
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投稿时间:2022-11-15     修订日期:2022-12-07     录用日期:2022-12-07     网络发布日期:2023-02-13
中文摘要: 采用溶胶-凝胶法制备了MnCeTmyOx/TiO2(y为Tm/Mn摩尔比,y=0.1,0.3,0.5)低温SCR脱硝催化剂,研究和分析了TmOx对催化剂脱硝性能的影响。所研制的MnCeTmOx/TiO2催化剂提高了以氨为还原剂的低温选择性催化还原(SCR)脱硝性能,并采用XRD、NH3-TPD分析探究了TmOx的作用及内在机制。结果表明,当y=0.3时,催化剂具有最佳的脱硝效果,在150 ℃具有95%以上的NOx转化率。对催化剂进行了稳定性测试和不同空速下的性能测试结果表明,MnCeTm0.3Ox/TiO2催化剂具有良好的稳定性,且在两种空速下均能保持优异的低温NH3-SCR脱硝性能。
Abstract:A low-temperature SCR denitration catalyst, MnCeTmyOx/TiO2 (y is molar ratio of Tm/Mn, y=0.1,0.3,0.5), was prepared by sol-gel method. The effect of TmOx on denitration performance of the catalyst was studied and analyzed. The developed MnCeTmOx/TiO2 catalyst improves the denitration performance of low-temperature selective catalytic reduction (SCR) with ammonia as reductant. The action and internal mechanism of TmOx were investigated by XRD and NH3-TPD analysis. The results show that when y=0.3, the catalyst has the best denitration effect, with 95% above NOx conversion rate at 150 ℃. At the same time, The test results of stability and performance of the catalyst performed at different space velocities show that the MnCeTm0.3Ox/TiO2 catalyst has good stability, and can also maintain excellent low-temperature NH3-SCR denitration performance at both space velocities.
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基金项目:新疆维吾尔自治区重大科技专项(2022A01002-2)
引用文本:
刘康,魏博,王珊,王建江,陈丽娟.铥改性MnCeOx/TiO2催化剂在氨中低温还原NOx的优越性能[J].有色金属(冶炼部分),2023(3):111-117.
LIU Kang,WEI Bo,WANG Shan,WANG Jian-jiang,CHEN Li-juan.Superior Performance of Thulium-Modified MnCeOx/TiO2 Catalysts for NOx Reduction at Low Temperature in Ammonia[J].Nonferrous Metals (Extractive Metallurgy),2023(3):111-117.

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