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投稿时间:2022-11-08 修订日期:2022-11-27 录用日期:2022-11-28 网络发布日期:2023-02-13
投稿时间:2022-11-08 修订日期:2022-11-27 录用日期:2022-11-28 网络发布日期:2023-02-13
中文摘要: 以铁含量为35%的氰渣为研究对象,研究了焙烧温度、焙烧时间及碳氧比对煤基磁化焙烧过程的影响,并采用化学分析、XRD、SEM、热重分析等分析手段对含铁氧化物的转变过程进行表征。随着焙烧温度的提高,铁氧化物的物相转变过程为Fe2O3→Fe3O4→FeO。随着磁化焙烧焙烧时间的延长,尾渣中的Fe2O3首先被C还原为Fe3O4,还原得到的Fe3O4可被空气中的O2重新氧化为Fe2O3。碳氧比较低时,磁化率接近2.33;当碳氧比超过3时,过量的煤与尾渣混合,Fe2O3还原反应不完全;在焙烧温度645 ℃、焙烧时间45 min、碳氧比3的优化焙烧条件下,得到焙烧矿的磁化率为2.34。
Abstract:Effects of roasting temperature, roasting time and ratio of carbon to oxygen on roasting process of coal-based magnetization were investigated, and the transformation process of iron-containing oxides was characterized by chemical analysis, XRD, SEM and thermogravimetric analysis. With the increase of roasting temperature, the transformation process of physical phase of iron-containing oxides is Fe2O3→Fe3O4→FeO. With the extension of roasting time of magnetization roasting, Fe2O3 in the tailings is first reduced to Fe3O4 by carbon, and the reduced Fe3O4 can be re-oxidized to Fe2O3 by oxygen in air. Under low ratio of carbon to oxygen conditions, the magnetization rate is close to 2.33. When the ratio of carbon to oxygen exceeds 3, the excess coal is mixed with the tailings, and resulting the incomplete reduction of Fe2O3. The magnetization rate of roasted ore is 2.34 under the optimum roasting conditions including roasting temperature of 645 ℃, roasting time of 45 min, and ratio of carbon to oxygen of 3.
文章编号: 中图分类号: 文献标志码:
基金项目:中央高校基本科研业务费资助项目(N182506003)
| 作者 | 单位 | |
| 衡振平 | 郑州金泉矿冶设备有限公司 | 89425463@qq.com |
| 谢锋* | 东北大学 冶金学院 | xief@smm.neu.edu.cn |
| 孙留根 | 东北大学 冶金学院 | |
| 韩路洋 | 东北大学 冶金学院 | |
| 董凯伟 | 东北大学 冶金学院 | |
| 白云龙 | 东北大学 冶金学院 |
引用文本:
衡振平,谢锋,孙留根,韩路洋,董凯伟,白云龙.含铁氰渣磁化焙烧回收铁精矿[J].有色金属(冶炼部分),2023(3):39-46.
HEN Zhen-ping,XIE Feng,SUN Liu-gen,HAN Lu-yang,DONG Kai-wei,BAI Yun-long.Recovery of Iron Concentrate from Ferrous Cyanide Residue by Magnetization Roasting[J].Nonferrous Metals (Extractive Metallurgy),2023(3):39-46.
衡振平,谢锋,孙留根,韩路洋,董凯伟,白云龙.含铁氰渣磁化焙烧回收铁精矿[J].有色金属(冶炼部分),2023(3):39-46.
HEN Zhen-ping,XIE Feng,SUN Liu-gen,HAN Lu-yang,DONG Kai-wei,BAI Yun-long.Recovery of Iron Concentrate from Ferrous Cyanide Residue by Magnetization Roasting[J].Nonferrous Metals (Extractive Metallurgy),2023(3):39-46.

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