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投稿时间:2022-10-16 修订日期:2022-11-07 录用日期:2022-11-08 网络发布日期:2023-02-13
投稿时间:2022-10-16 修订日期:2022-11-07 录用日期:2022-11-08 网络发布日期:2023-02-13
中文摘要: 为探究酸法地浸过程中Fe3+作为氧化剂时铀的浸出情况,通过使用模拟软件PHREEQE建立模型,观察浸出液各组分的浓度及迁移变化,揭示氧化剂Fe3+与浸出铀之间的关系。结果表明:作为氧化剂的Fe3+促使铀矿的溶解及Fe2+的出现,随着铀的浸出结束,Fe3+的浓度趋于稳定;且铀矿的溶解速率与Fe3+、Fe2+的增长速率密切相关。Fe3+的浓度增长变快时,Fe2+的浓度增长及铀矿的溶解也加快;随着铀矿的溶解速率降为零后,Fe2+的增长速率也趋近于零,氧化剂Fe3+的增长速率也降为零。
Abstract:In order to explore the leaching situation of uranium with Fe3+ as oxidant in acid leaching process, the simulation software PHREEQE was used to establish a model to observe the concentration and migration changes of each component of the leaching solution, so as to reveal the relationship between the oxidant Fe3+ and leached uranium. The results show that as an oxidant, Fe3+ promotes the dissolution of uranium ore and the appearance of Fe2+. With the end of uranium leaching, Fe3+ concentration tends to be stable. The dissolution rate of uranium ore is closely related to the growth rate of Fe3+ and Fe2+. When the concentration of Fe3+ rises rapidly, Fe2+ concentration rises and dissolution of uranium ore accelerates. As the dissolution rate of uranium ore drops to zero, the growth rate of Fe2+ approaches zero, and the growth rate of oxidant Fe3+ also drops to zero.
文章编号: 中图分类号: 文献标志码:
基金项目:国家自然科学基金资助项目(42062017,U1967209,41201500)
| 作者 | 单位 | |
| 刘春雨 | 东华理工大学 | 1132853425@qq.com |
| 李寻* | 东华理工大学 | 317749537@qq.com |
| 罗跃 | 东华理工大学 | |
| 高柏 | 东华理工大学 | |
| 吴慧 | 东华理工大学 | |
| 刘亚洲 | 东华理工大学 |
| Author Name | Affiliation | |
| LIU Chun-yu | East China University of Technology | 1132853425@qq.com |
| LI Xun | East China University of Technology | 317749537@qq.com |
| LUO Yue | ||
| GAO Bai | ||
| WU Hui | ||
| LIU Ya-Zhou |
引用文本:
刘春雨,李寻,罗跃,高柏,吴慧,刘亚洲.酸法浸铀过程中Fe3+与浸出铀关系的数值模拟[J].有色金属(冶炼部分),2023(3):88-94.
LIU Chun-yu,LI Xun,LUO Yue,GAO Bai,WU Hui,LIU Ya-Zhou.Numerical Simulation of Relationship between Fe3+ and Leached Uranium during Acid Leaching[J].Nonferrous Metals (Extractive Metallurgy),2023(3):88-94.
刘春雨,李寻,罗跃,高柏,吴慧,刘亚洲.酸法浸铀过程中Fe3+与浸出铀关系的数值模拟[J].有色金属(冶炼部分),2023(3):88-94.
LIU Chun-yu,LI Xun,LUO Yue,GAO Bai,WU Hui,LIU Ya-Zhou.Numerical Simulation of Relationship between Fe3+ and Leached Uranium during Acid Leaching[J].Nonferrous Metals (Extractive Metallurgy),2023(3):88-94.

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