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有色金属(冶炼部分):2023,(3):88-94
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酸法浸铀过程中Fe3+与浸出铀关系的数值模拟
刘春雨, 李寻, 高柏, 罗跃, 吴慧, 刘亚洲
(东华理工大学)
Numerical Simulation of Relationship between Fe3+ and Leached Uranium during Acid Leaching
LIU Chun-yu, LI Xun, GAO Bai, LUO Yue, WU Hui, LIU Ya-Zhou
(East China University of Technology)
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投稿时间:2022-10-16     修订日期:2022-11-07     录用日期:2022-11-08     网络发布日期:2023-02-13
中文摘要: 为探究酸法地浸过程中Fe3+作为氧化剂时铀的浸出情况,通过使用模拟软件PHREEQE建立模型,观察浸出液各组分的浓度及迁移变化,揭示氧化剂Fe3+与浸出铀之间的关系。结果表明:作为氧化剂的Fe3+促使铀矿的溶解及Fe2+的出现,随着铀的浸出结束,Fe3+的浓度趋于稳定;且铀矿的溶解速率与Fe3+、Fe2+的增长速率密切相关。Fe3+的浓度增长变快时,Fe2+的浓度增长及铀矿的溶解也加快;随着铀矿的溶解速率降为零后,Fe2+的增长速率也趋近于零,氧化剂Fe3+的增长速率也降为零。
Abstract:In order to explore the leaching situation of uranium with Fe3+ as oxidant in acid leaching process, the simulation software PHREEQE was used to establish a model to observe the concentration and migration changes of each component of the leaching solution, so as to reveal the relationship between the oxidant Fe3+ and leached uranium. The results show that as an oxidant, Fe3+ promotes the dissolution of uranium ore and the appearance of Fe2+. With the end of uranium leaching, Fe3+ concentration tends to be stable. The dissolution rate of uranium ore is closely related to the growth rate of Fe3+ and Fe2+. When the concentration of Fe3+ rises rapidly, Fe2+ concentration rises and dissolution of uranium ore accelerates. As the dissolution rate of uranium ore drops to zero, the growth rate of Fe2+ approaches zero, and the growth rate of oxidant Fe3+ also drops to zero.
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基金项目:国家自然科学基金资助项目(42062017,U1967209,41201500)
引用文本:
刘春雨,李寻,罗跃,高柏,吴慧,刘亚洲.酸法浸铀过程中Fe3+与浸出铀关系的数值模拟[J].有色金属(冶炼部分),2023(3):88-94.
LIU Chun-yu,LI Xun,LUO Yue,GAO Bai,WU Hui,LIU Ya-Zhou.Numerical Simulation of Relationship between Fe3+ and Leached Uranium during Acid Leaching[J].Nonferrous Metals (Extractive Metallurgy),2023(3):88-94.

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