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投稿时间:2022-10-12 修订日期:2022-10-17 录用日期:2022-10-19 网络发布日期:2023-06-16
投稿时间:2022-10-12 修订日期:2022-10-17 录用日期:2022-10-19 网络发布日期:2023-06-16
中文摘要: 铟作为一种多用途的稀散金属,应用前景十分广泛,若能高效回收利用,将具有极大的经济效益。但由于铟的存在形式复杂,导致铟的提取十分困难,因此如何从含铟物料中高效回收铟成为技术关键。以某复杂铅基多金属固废协同冶炼过程产生的含铅烟灰为原料,采用“硫酸化焙烧—多段逆流水浸”工艺实现铟的高效浸出,考察了焙烧过程温度、时间、酸料比(质量比),以及水浸过程温度、时间、液固比对铟浸出率的影响。结果表明:在焙烧温度330 ℃、焙烧时间4 h、酸料比0.5 g/g,常温水浸,水浸时间2 h、液固比5 g/g的条件下,铟的浸出效果最好。与常规浸出及氧压浸出相比,铟的浸出率提高到96%以上,实现了铟的高效浸出。
Abstract:Indium, as a multi-purpose rare metal, has a wide range of application prospects and will have great economic benefits if it can be recycled efficiently. However, the complex form of the existence of indium makes the extraction of indium very difficult, so how to efficiently recover indium from indium-bearing materials becomes the key problem in technology. The process of "sulfation roasting and multi-stage countercurrent water leaching" was adopted to realize the efficient leaching of indium applying the lead-bearing soot from the complex lead-based polymetallic solid waste co-smelting process as raw materials. The effects of roasting temperature, roasting time, mass ratio of acid to material, and water leaching temperature, time, and ratio of liquid to solid on leaching rate of indium were investigated. The results show that the best leaching effect of indium is achieved under the conditions including roasting temperature of 330 ℃, roasting time of 4 h, mass ratio of acid to material of 0.5 g/g, water leaching at room temperature, water leaching time of 2 h and ratio of liquid to solid of 5 g/g. Compared with conventional leaching and oxygen-pressure leaching, the leaching rate of indium rises to 96% above, and the efficient leaching of indium is achieved.
文章编号: 中图分类号: 文献标志码:
基金项目:国家重点研发计划项目(2019YFC1907304)
| 作者 | 单位 | |
| 李诗丽* | 矿冶科技集团有限公司 | lishili202105@163.com |
| 邹小平 | 矿冶科技集团有限公司 | |
| 陈露露 | 矿冶科技集团有限公司 | |
| 朱坤娥 | 矿冶科技集团有限公司 |
| Author Name | Affiliation | |
| LI Shi-li | BGRIMM TECHNOLOGY GROUP | lishili202105@163.com |
| ZOU Xiao-ping | ||
| CHEN Lu-lu | ||
| ZHU Kun-e |
引用文本:
李诗丽,邹小平,陈露露,朱坤娥.含铅烟灰高效浸出铟的工艺研究[J].有色金属(冶炼部分),2023(7):43-47.
LI Shi-li,ZOU Xiao-ping,CHEN Lu-lu,ZHU Kun-e.High Efficient Leaching of Indium from Lead-bearing Soot[J].Nonferrous Metals (Extractive Metallurgy),2023(7):43-47.
李诗丽,邹小平,陈露露,朱坤娥.含铅烟灰高效浸出铟的工艺研究[J].有色金属(冶炼部分),2023(7):43-47.
LI Shi-li,ZOU Xiao-ping,CHEN Lu-lu,ZHU Kun-e.High Efficient Leaching of Indium from Lead-bearing Soot[J].Nonferrous Metals (Extractive Metallurgy),2023(7):43-47.

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