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投稿时间:2022-06-21 修订日期:2022-06-27 录用日期:2022-07-04 网络发布日期:2022-10-14
投稿时间:2022-06-21 修订日期:2022-06-27 录用日期:2022-07-04 网络发布日期:2022-10-14
中文摘要: 石棉尾矿酸浸分离制备系列高纯硅镁化合物粉体材料是石棉尾矿高值化利用的重要途径,但石棉尾矿的酸浸液中除主要含有Mg2+外,还含有如Fe3+、Fe2+等杂质离子。以石棉尾矿经焙烧、酸浸后的高镁酸性滤液为原料,氨水为中和剂,对滤液进行沉淀除铁,采用分光光度法测定滤液中铁离子的浓度,XRD、FT-IR等分析沉淀产物的物相结构变化。结果表明,在反应终点pH=4.5、反应温度80 ℃、反应时间10 min条件下,沉淀物主要由针铁矿和黄铵铁矾构成,铁的去除率可达99.71%,镁损失率仅为3.39%,悬浊液的过滤速度为3.46 mL/min,产物过滤性能好,铁离子去除率高。
Abstract:Acid leaching separation of asbestos tailings to prepare a series of high-purity silicon-magnesium compound powder materials is an important way of high-value utilization of asbestos tailings, but the acid leaching solution of asbestos tailings mainly contains Mg2+, as well as contains impurities such as Fe3+, Fe2+ and so on. The high magnesium acid filtrate after roasting and acid leaching of asbestos tailings was used as raw material,and ammonia water was used as neutralizer to precipitate iron in the filtrate. The concentration of iron ion in the filtrate was determined by spectrophotometry, the phase and structure of precipitated products were analyzed by XRD and FT-IR. The results show that under the conditions including pH value of 4.5, reaction temperature of 80 ℃, and reaction time of 10 min, the sediment is mainly composed of goethite and jarosite, removal rate of iron is 99.71%, loss rate of magnesium is only 3.39%, and filtration rate of suspension is 3.46 mL/min. The product filtration performance is good.
文章编号: 中图分类号: 文献标志码:
基金项目:国家自然科学基金资助项目(42072048);四川省级知识产权专项资金项目(2022-ZS-00031)
| 作者 | 单位 | |
| 储凌燕 | 西南科技大学环境与资源学院 | yanling_chu@163.com |
| 孙红娟* | 西南科技大学环境与资源学院 | sunhongjuan@swust.edu.cn |
| 彭同江 | 西南科技大学环境与资源学院 |
引用文本:
储凌燕,孙红娟,彭同江.基于针铁矿法对石棉尾矿酸浸液高效除铁[J].有色金属(冶炼部分),2022(11):9-16.
CHU Ling-Yan,SUN Hong-Juan,PENG Tong-Jiang.Iron Removal from Acid Leaching Solution of Asbestos Tailings by Goethite Method[J].Nonferrous Metals (Extractive Metallurgy),2022(11):9-16.
储凌燕,孙红娟,彭同江.基于针铁矿法对石棉尾矿酸浸液高效除铁[J].有色金属(冶炼部分),2022(11):9-16.
CHU Ling-Yan,SUN Hong-Juan,PENG Tong-Jiang.Iron Removal from Acid Leaching Solution of Asbestos Tailings by Goethite Method[J].Nonferrous Metals (Extractive Metallurgy),2022(11):9-16.

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