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投稿时间:2022-06-13 修订日期:2022-06-19 录用日期:2022-06-27 网络发布日期:2022-09-16
投稿时间:2022-06-13 修订日期:2022-06-19 录用日期:2022-06-27 网络发布日期:2022-09-16
中文摘要: 锂电解槽相比于镁、铝电解槽电流小,产量低,随着市场对金属锂的需求逐年上升,开发设计大电流锂电解槽可以为工业实际运用提供参考。以大电流锂电解槽为研究对象,运用有限元软件COMSOL建立锂电解槽电解质-氯气气液两相流模型,采用Euler-Euler两相流模型并耦合k-ε模型用于求解电解液速度,分析了槽内电势、电流密度及流场分布规律。结果表明,电解槽内的极间空间顶部皆存回流情况,越靠近电解槽内部,回流现象越明显;电解槽内壁处湍流黏度较高,涡流强度大;每对电极对应的电解质循环具有明显的界限,随着阴阳极对靠近电解槽内壁面数增加,电解液循环效果越好。
Abstract:Compared with magnesium and aluminum electrolytic cells, lithium electrolytic cell current is small and has a low output, the market demand for lithium metal rising year by year, and the development and design of large current lithium electrolytic cell can provide a reference for the actual use of industry. A two-phase flow model of electrolyte-chlorine gas was established by COMSOL, Euler-Euler two-phase flow model coupled with k-ε model was used to solve the electrolyte velocity, and electric potential, current density, and flow field distribution in the electrolytic cell were analyzed. The results show that there is reflux at the top of the interelectrode space in the electrolytic cell, and the closer to the electrolytic cell, the more obvious the reflux phenomenon. The inner wall of the cell has high turbulence viscosity and eddy current intensity. The electrolyte cycle corresponding to each pair of electrodes has an obvious limit, and the electrolyte cycle is better with the increase in the number of anode and cathode pairs close to the inner wall of the electrolytic cell.
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基金项目:国家自然科学基金资助项目(U20A20147)
| 作者 | 单位 | |
| 吴荔荔 | 华东理工大学盐湖资源综合利用国家工程研究中心 | 2582900029@qq.com |
| 李文英 | 上海飞机制造有限公司 | |
| 路贵民* | 华东理工大学盐湖资源综合利用国家工程研究中心 | gmlu@ecust.edu.cn |
引用文本:
吴荔荔,李文英,路贵民.大型锂电解槽流场分析[J].有色金属(冶炼部分),2022(10):48-57.
WU Li-li,LI Wen-ying,LU Gui-min.Flow Field Analysis of High Current Lithium Electrolytic Cell[J].Nonferrous Metals (Extractive Metallurgy),2022(10):48-57.
吴荔荔,李文英,路贵民.大型锂电解槽流场分析[J].有色金属(冶炼部分),2022(10):48-57.
WU Li-li,LI Wen-ying,LU Gui-min.Flow Field Analysis of High Current Lithium Electrolytic Cell[J].Nonferrous Metals (Extractive Metallurgy),2022(10):48-57.

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