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有色金属(冶炼部分):2022,(10):72-80
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地浸采铀过程中的矿物溶解沉淀特征
丰章哲1, 刘金辉1, 阳奕汉2, 王如意2, 刑拥国3, 梁大业2
(1.东华理工大学;2.中核内蒙古矿业有限公司;3.中核矿业科技有限公司)
Characterization of Mineral Dissolution Precipitation during Uranium In-situ Leaching
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投稿时间:2022-06-10     修订日期:2022-06-15     录用日期:2022-06-20     网络发布日期:2022-09-16
中文摘要: 铀的原位浸出是通过溶浸液与铀矿物相互作用来实现的,地浸采铀过程中溶浸液与含矿层中各种矿物反应,会使溶浸液中各种离子组分大量增高,当离子浓度达到饱和或过饱和时,又会产生化学沉淀,造成含矿层堵塞。以巴彦乌拉铀矿C12采区为研究对象,根据浸出液化学成分数据,通过地球化学模拟计算采区运行过程中矿物饱和指数,研究地浸过程中矿物的溶解-沉淀特征。计算结果表明,酸法地浸过程中石膏、Fe(OH)3、针铁矿和赤铁矿是地浸采铀过程中易产生沉淀的矿物。地浸6.5天后石膏即处于沉淀状态;Fe(OH)3在pH大于6.71~6.89条件下、针铁矿在pH大于4.6~5.0条件下、赤铁矿在pH大于4.62~4.87时处于沉淀状态。pH是影响矿物溶解与沉淀的关键因素。
Abstract:In situ leaching of uranium is achieved by the interaction between the leach solution and uranium minerals. The reaction between the leach solution and various minerals in the ore-bearing layer during the process of uranium extraction by ground leaching will cause a large increase of various ionic components in the leach solution,and when the ionic concentration reaches saturation or supersaturation, chemical precipitation will be produced to cause blockage of the ore-bearing layer. For this reason,it is of great importance to carry out research on the dissolution precipitation characteristics of minerals in ground leaching. In this paper,the dissolution-precipitation characteristics of minerals in the ground leaching process were studied by calculating the mineral saturation index during the operation of the mining area through geochemical simulation based on the chemical composition data Uranium in-situ leaching is achieved by interaction between leaching solution and uranium minerals. The reaction between leaching solution and various minerals in ore-bearing layer during the process of uranium extraction by in-situ leaching will cause greatly increase of various ionic components in leaching solution, and when the ionic concentration reaches saturation or supersaturation, chemical precipitation will be produced to cause blockage of ore-bearing layer. The dissolution-precipitation characteristics of minerals during in-situ leaching were studied by calculating mineral saturation index during operation of mining area through geochemical simulation based on chemical composition data of leaching solution in the C12 mining area of Bayan-Ula uranium mine. The calculation results show that gypsum, Fe(OH)3, goethite, and hematite are easy to precipitate during uranium in-situ leaching. After 6.5 days of in-situ leaching, gypsum is in a state of precipitation. Fe(OH)3, goethite and hematite are in the precipitation state when pH value is greater than 6.71—6.89, 4.6—5.0 and 4.62—4.87, respectively. The key factor affecting dissolution and precipitation of minerals is pH value.
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基金项目:国家自然科学基金资助项目(U1967209);中国铀业有限公司—东华理工大学核资源与环境国家重点实验室联合创新基金资助项目(NRE-17)
引用文本:
丰章哲,刘金辉,阳奕汉,王如意,刑拥国,梁大业.地浸采铀过程中的矿物溶解沉淀特征[J].有色金属(冶炼部分),2022(10):72-80.
FENG Zhang-zhe,LIU Jin-hui,YANG Yi-han,WANG Ru-yi,XING Yong-guo,LIANG Da-ye.Characterization of Mineral Dissolution Precipitation during Uranium In-situ Leaching[J].Nonferrous Metals (Extractive Metallurgy),2022(10):72-80.

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