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有色金属(冶炼部分):2022,(9):133-139
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燃煤渣-花岗岩粉基地质聚合物的制备
郑戈弋1, 周海林2, 黄青叶2, 姚瞬雨2, 李典彤2, 阚宏博2, 包申旭2
(1.武汉理工大学 资源与环境工程学院;2.武汉理工大学资源与环境工程学院)
Preparation and Performance Characterization of Granite Powder-Burnt Coal Cinder-Based Geoploymer
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投稿时间:2022-06-01     修订日期:2022-06-02     录用日期:2022-06-09     网络发布日期:2022-08-11
中文摘要: 采用燃煤渣和花岗岩粉为主要原料制备地质聚合物。当燃煤渣与花岗岩粉的质量比为10,NaOH溶液(6 mol/L)与燃煤渣比值为0.25 mL/g,水玻璃与燃煤渣比值为0.18 mL/g,养护温度60 ℃,带模养护时间2天时,脱模后得到的最终产物在28天的抗压强度可达20.96 MPa。结果表明,氢氧化钠溶液对试样抗压强度的影响是硅铝溶解、泛霜及孔隙率变化等多重因素综合作用的结果。水玻璃的加入并不能使试样的矿物组成发生较大改变,但可以显著提高反应体系中硅酸盐低聚离子的浓度,增加凝胶的生成量。花岗岩粉在碱激发的条件下未表现出明显的地质聚合能力,但适量掺入仍可以起到骨料和填充作用,提高地质聚合物的抗压强度。本研究拓宽了制备地质聚合物的原料来源,为燃煤渣和花岗岩粉在建筑材料方面的利用提供了参考。
Abstract:Geopolymers was prepared by applying burnt coal cinder (BCC) and granite powder (GP) as main raw materials. When the mass ratio of BCC to GP is 10, ratio of NaOH solution (6 mol/L) to BCC is 0.25 mL/g, ratio of waterglass to BCC is 0.18 mL/g, curing temperature is 60 ℃, and curing with mold for 2 days, the compressive strength (28 d) of the final product obtained after demolding can reach 20.96 MPa. The results show that the influence of NaOH solution on compressive strength of sample is the result of combined effect of multiple factors including dissolution of silica and aluminum, phenomenon of efflorescence and porosity. The addition of waterglass cannot make the mineral composition of sample change obviously, but it can significantly increase the concentration of silicate oligomeric ions in reaction system and increase generation of gels. GP does not show obvious geopolymerization ability under the condition of alkali activation, but it can still play the role of aggregate and filling, improving compressive strength of geopolymer. This study broadens the sources of raw materials for preparation of geopolymers, and provides a reference for utilization of BCC and GP in building materials.
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基金项目:武汉理工大学自主创新研究基金(2021-ZH-A1-01);国家重点研发计划项目课题(2018YFC1900606-3)
引用文本:
郑戈弋,周海林,黄青叶,姚瞬雨,李典彤,阚宏博,包申旭.燃煤渣-花岗岩粉基地质聚合物的制备[J].有色金属(冶炼部分),2022(9):133-139.
ZHENG Ge-yi,ZHOU Hai-lin,HUANG Qing-ye,YAO Shun-yu,LI Dian-tong,KAN Hong-bo,BAO Shen-xu.Preparation and Performance Characterization of Granite Powder-Burnt Coal Cinder-Based Geoploymer[J].Nonferrous Metals (Extractive Metallurgy),2022(9):133-139.

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