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投稿时间:2022-05-23 修订日期:2022-05-30 录用日期:2022-06-06 网络发布日期:2022-09-16
投稿时间:2022-05-23 修订日期:2022-05-30 录用日期:2022-06-06 网络发布日期:2022-09-16
中文摘要: 针对冶金行业产生的含铅废水导致的环境污染问题,以太行山脉盛产的野生冬凌草为载体,采用液相化学还原法制备了冬凌草负载纳米零价铁(RR-nZVI),并用于去除水中的Pb2+,详细考察了酸度、温度、RR-nZVI投加量、Pb2+初始浓度和反应时间对Pb2+去除率的影响。通过FTIR、XRD、SEM等手段对RR-nZVI去除Pb2+的机理进行分析。结果表明,RR-nZVI投加量0.6 g/L、pH=5.0、Pb2+初始浓度200 mg/L、室温下反应60 min时,Pb2+的去除率达到了99.9%,吸附量达到394.7 mg/g。动力学试验表明,RR-nZVI对溶液中Pb2+的吸附符合Lagergren准二级动力学模型,吸附过程主要受化学吸附控制。Langmuir模型能较好地描述RR-nZVI对Pb2+的吸附过程,吸附以单层吸附为主。当Pb2+的初始浓度小于10 mg/L时,滤液中的Fe2+浓度低于国家《铅、锌工业污染物排放标准(GB 25466—2010)》中规定的限量要求,不会对环境造成二次污染,为含Pb2+废水的处理提供了一种有效的可供选择的材料。
Abstract:To address environmental pollution caused by wastewater containing lead produced in metallurgy industries, Rabdosia rubescens obtained from Taihang Mountains was used as carrier, Rabdosia rubescens loaded nano-zero-valent iron (RR-NZVI) was prepared by liquid phase chemical reduction method, and used to remove Pb2+ from water. Effects of pH value, temperature, RR-nZVI dosage, initial concentration of Pb2+ and reaction time on removal efficiency of Pb2+ were investigated.FTIR, SEM and XRD were used to characterize the mechanisms of Pb2+ removal. The results show that removal efficiency of Pb2+ is 99.9% and the maximum adsorption capacity of Pb2+ is 394.7 mg/g under the conditions including RR-nZVI dosage of 0.8 g/L, pH=5.0, initial concentration of Pb2+ of 200 mg/L, and reaction time of 60 min at room temperature. The results of kinetic experiments show that the adsorption kinetics of Pb2+ on RR-nZVI in solution is in accordance with Lagergren pseudo–second-order model, which is mainly controlled by chemical adsorption. The isothermal adsorption of Pb2+ on RR-nZVI could be well fitted with the Langmuir isothermal adsorption model, which suggested that the adsorption of Pb2+ from solution is mainly monolayer adsorption. When the initial Pb2+ concentration is less than 10 mg/L, Fe2+ concentration in filtrate is lower than the limited demand of Emission Standard of Pollutants for Lead and Zinc Industry(GB 25466—2010), which would not cause secondary pollution to the environment. Consequently, it can provide an effective alternative material for treatment of wastewater containing Pb2+.
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基金项目:河南省2020年科技发展计划项目(202102210259);济源市2020年度科技发展计划项目(20022008)
| 作者 | 单位 | |
| 左国强* | 济源职业技术学院冶金化工系 | guoqiangzuo@126.com |
| 李晓乐 | 济源职业技术学院冶金化工系 | |
| 张晓杰 | 济源职业技术学院冶金化工系 | |
| 苏小莉 | 济源职业技术学院冶金化工系 | |
| 张文生 | 济源职业技术学院冶金化工系 |
引用文本:
左国强,李晓乐,张晓杰,苏小莉,张文生.冬凌草负载纳米零价铁吸附废水中的Pb2+[J].有色金属(冶炼部分),2022(10):115-123.
ZUO Guo-qiang,LI Xiao-le,ZHANG Xiao-jie,SU Xiao-li,ZHANG Wen-sheng.Adsorption of Pb2+ in Wastewater by Nanoscale Zero-valent Iron Supported by Rabdosia Rubescens[J].Nonferrous Metals (Extractive Metallurgy),2022(10):115-123.
左国强,李晓乐,张晓杰,苏小莉,张文生.冬凌草负载纳米零价铁吸附废水中的Pb2+[J].有色金属(冶炼部分),2022(10):115-123.
ZUO Guo-qiang,LI Xiao-le,ZHANG Xiao-jie,SU Xiao-li,ZHANG Wen-sheng.Adsorption of Pb2+ in Wastewater by Nanoscale Zero-valent Iron Supported by Rabdosia Rubescens[J].Nonferrous Metals (Extractive Metallurgy),2022(10):115-123.

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