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有色金属(冶炼部分):2022,(10):15-21
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粗硫酸镍溶液直接萃取镍的工艺研究
邬建辉, 王翊民, 严润
(中南大学冶金与环境学院)
Study on Nickel Extraction from Crude Nickel Sulfate Solution
WU Jian-hui, WANG Yi-mim, YAN Run
(School of Metallurgy & Environment,Central South University,Hunan Changsha)
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投稿时间:2022-05-12     修订日期:2022-05-19     录用日期:2022-05-21     网络发布日期:2022-09-16
中文摘要: 使用新型萃取剂HBL110从粗硫酸镍溶液中直接萃取镍。结果表明,萃取的较优条件为:萃取剂皂化率60%、萃取相比VO︰VA=2︰1、料液起始pH=2.2、萃取时间5 min,经5级逆流萃取,镍萃取率为98.63%,铁、钴、锌、钙、镁的萃取分别为10.41%、22.86%、8.42%、1.75%、1.38%。有机相经酸洗后反萃,反萃的较优条件为:反萃剂H2SO4浓度1.0 mol/L、反萃相比VO︰VA=4︰1、反萃时间5 min,该条件下进行4级逆流反萃,镍的反萃率为98.85%,反萃液镍浓度为31.11 g/L,且反萃液杂质含量低。
中文关键词: 粗硫酸镍  HBL110  萃取  反萃
Abstract:Nickel was directly extracted from crude nickel sulfate solution with new extractant HBL110. The results show that after 5-stage countercurrent extraction, the extraction efficiency of nickel is 98.63%, and extraction efficiency of Fe, Co, Zn, Ca and Mg is 10.41%, 22.86%, 8.42%, 1.75%, and 1.38% respectively under the optimum extraction conditions including saponification ratio of extractant of 60%, initial pH value of 2.2, phase ratio VO︰VA=2︰1, and extraction time of 5 min. Before stripping the organic phase is washed with dilute acid solution, after 4-stage countercurrent stripping, the stripping efficiency of nickel is 98.85%, and nickel concentration in stripping solution is 31.11 g/L with low impurity content under the optimum stripping conditions including concentration of stripping agent of 1.0 mol/L, phase ratio of VO︰VA=4︰1, and stripping time of 5 min.
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基金项目:江西省科技支撑计划工业领域重大项目(20152ACE50023)
引用文本:
邬建辉,王翊民,严润.粗硫酸镍溶液直接萃取镍的工艺研究[J].有色金属(冶炼部分),2022(10):15-21.
WU Jian-hui,WANG Yi-mim,YAN Run.Study on Nickel Extraction from Crude Nickel Sulfate Solution[J].Nonferrous Metals (Extractive Metallurgy),2022(10):15-21.

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