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有色金属(冶炼部分):2022,(8):15-19
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镍钴锰三元前驱体废料与硫化镍废料的联合浸出
付海阔, 沈恒冠, 赵喜太, 段辉, 廖玉俐, 张玲丽
(湖南中伟新能源科技有限公司)
Integrated Leaching of Wastes of Nickel-Cobalt-Manganese Ternary Precursor and Nickel Sulfide
FU Hai-kuo, SHEN Heng-guan, ZHAO Xi-tai, DUAN Hui, LIAO Yu-li, ZHANG Ling-li
(Hunan CNGR New Energy Technology Co.Ltd)
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投稿时间:2022-04-14     修订日期:2022-04-29     录用日期:2022-05-06     网络发布日期:2022-07-13
中文摘要: 研究了镍钴锰三元前驱体废料和硫化镍废料联合氧化还原浸出过程。在下述最佳反应条件下:硫化镍废料与镍钴锰三元前驱体废料质量比1/5、反应初始酸度4 mol/L、反应温度90 ℃、反应液固比4、反应时间6 h,镍钴锰三元前驱体废料中锰的浸出率和硫化镍废料的利用率分别达到99.89%和92.60%,浸出渣可以返回继续还原浸出镍钴锰三元前驱体废料。本工艺避免了镍钴锰三元前驱体废料单独浸出的还原剂消耗和硫化镍废料单独浸出的氧化剂消耗,实现了镍钴锰三元前驱体废料和硫化镍废料的协同浸出。
Abstract:Integrated leaching of nickel-cobalt-manganese ternary precursor waste and nickel sulfide waste was studied. The experimental results show that recovery of manganese in nickel-cobalt-manganese ternary precursor waste and utilization of nickel sulfide waste is 99.89% and 92.60% respectively under the optimum conditions including mass ratio of nickel sulfide waste to nickel-cobalt-manganese ternary precursor waste of 1/5, initial acidity of reaction of 4 mol/L, reaction temperature of 90 ℃, L/S of 4, and reaction time of 6 h. The residue can be used for leaching nickel-cobalt-manganese ternary precursor waste as reductant. The objective of integrated leaching of nickel-cobalt-manganese ternary precursor waste and nickel sulfide waste is realized without any other additional oxidant or reductant.
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基金项目:2018年度湖南省科技厅创新创业技术投资项目(2018GK5013)
引用文本:
付海阔,沈恒冠,赵喜太,段辉,廖玉俐,张玲丽.镍钴锰三元前驱体废料与硫化镍废料的联合浸出[J].有色金属(冶炼部分),2022(8):15-19.
FU Hai-kuo,SHEN Heng-guan,ZHAO Xi-tai,DUAN Hui,LIAO Yu-li,ZHANG Ling-li.Integrated Leaching of Wastes of Nickel-Cobalt-Manganese Ternary Precursor and Nickel Sulfide[J].Nonferrous Metals (Extractive Metallurgy),2022(8):15-19.

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