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投稿时间:2022-02-14 修订日期:2022-03-06 录用日期:2022-03-07 网络发布日期:2022-05-11
投稿时间:2022-02-14 修订日期:2022-03-06 录用日期:2022-03-07 网络发布日期:2022-05-11
中文摘要: 为探索CO2+O2地浸采铀工艺在西北某砂岩型铀矿床应用的技术可行性,开展了地浸采铀现场条件试验。试验表明,向矿层水中注加O2,浸出液残留的溶解氧含量明显增加,但浸出液c(U)未见明显升高;在矿层水中原始c(HCO3-)为300 mg/L的条件下,向矿层水中同时注加CO2+O2,浸出液中c(HCO3-)仅上升至300~350 mg/L,c(U)未见明显升高;补加NH4HCO3使浸出剂中c(HCO3-)达到1 000 mg/L时,浸出液的c(U)随c(HCO3-)上升呈直线上升态势,c(U)峰值达到31.5 mg/L,c(U)与c(HCO3-)相关系数达0.95,呈强正相关性。研究表明,该砂岩型铀矿仅采用CO2+O2进行浸出,不能获得满足地浸工业要求的c(U);通过补加NH4HCO3并保持浸出液中c(HCO3-)达到800 mg/L时,浸出液c(U)出现明显上涨(峰值31.5 mg/L,平均25 mg/L以上)。该矿床技术可行的浸出工艺为“CO2+O2+NH4HCO3”地浸。
中文关键词: 地浸采铀 CO2+O2 浸出试验 CO2+O2+NH4HCO3
Abstract:In order to explore the technical feasibility of application of CO2+O2 in-situ leaching (ISL) technology in a sandstone type of uranium deposit in Northwest China, a field condition test of ISL uranium mining was carried out. The test results show that when O2 is added to groundwater, the dissolved O2 content of the leachate residue rises significantly, but there is no significant increase of c(U) in leaching fluid. When CO2 and O2 are added to the groundwater under the condition of original groundwater c(HCO3-) of 300 mg/L, the rise of c(HCO3-) in the leachate is not significant (only rises from 300 mg/L to 350 mg/L), and no significant increase is observed in c(U). By adding NH4HCO3 to make the leaching agent c(HCO3-) to 1 000 mg/L, c(U) in leachate rises straightly with the increase of c(HCO3-), and the peak of c(U) reaches 31.5 mg/L. The correlation coefficient of c(U) and c(HCO3-) is 0.95, and the two parameter shows a strong positive correlation. The research results show that this sandstone type uranium mine cannot meet the requirements of ISL only by CO2+O2 leaching process, by adding NH4HCO3 and keeping c(HCO3-) in solution reaches 800 mg/L, c(U) in leachate can meet the industrial production requirements of ISL (peak value is 31.5 mg/L, and the average concentration is 25 mg/L above). The technically feasible leaching process of this deposit is “CO2 + O2 + NH4HCO3” in-situ leaching.
文章编号: 中图分类号: 文献标志码:
基金项目:中核集团“青年英才”项目(中核科发[2021]272号)
| 作者 | 单位 | |
| 陶峰 | 东华理工大学 水资源与环境工程学院 | 17568323@qq.com |
| 张传飞 | 中核内蒙古矿业有限公司 | |
| 冯国平 | 新疆中核天山铀业有限公司 | |
| 于长贵 | 新疆中核天山铀业有限公司 | |
| 段柏山 | 新疆中核天山铀业有限公司 | |
| 陈梅芳* | 核工业北京化工冶金研究院 铀矿地浸所 | ziqiong0731@126.com |
| Author Name | Affiliation | |
| TAO Feng | East China University of Technology | 17568323@qq.com |
| ZHANG Chuan-fei | ||
| FENG Guo-ping | ||
| YU Chang-gui | ||
| DUAN Bai-shan | ||
| CHEN Mei-fang | ziqiong0731@126.com |
引用文本:
陶峰,张传飞,冯国平,于长贵,段柏山,陈梅芳.某砂岩型铀矿CO2+O2地浸采铀试验[J].有色金属(冶炼部分),2022(6):56-61.
TAO Feng,ZHANG Chuan-fei,FENG Guo-ping,YU Chang-gui,DUAN Bai-shan,CHEN Mei-fang.CO2+O2 In-situ Leaching of Uranium from a Sandstone Type Uranium Deposit[J].Nonferrous Metals (Extractive Metallurgy),2022(6):56-61.
陶峰,张传飞,冯国平,于长贵,段柏山,陈梅芳.某砂岩型铀矿CO2+O2地浸采铀试验[J].有色金属(冶炼部分),2022(6):56-61.
TAO Feng,ZHANG Chuan-fei,FENG Guo-ping,YU Chang-gui,DUAN Bai-shan,CHEN Mei-fang.CO2+O2 In-situ Leaching of Uranium from a Sandstone Type Uranium Deposit[J].Nonferrous Metals (Extractive Metallurgy),2022(6):56-61.

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