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有色金属(冶炼部分):2022,(6):37-42
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铝灰酸浸提铝过程动力学研究
袁杰[ ], 罗亮昆, 林安伟
(六盘水师范学院化学与材料工程学院)
Leaching Kinetics of Aluminum from Aluminum Dross with Hydrochloric Acid
YUAN Jie, LUO Liang-kun, LIN AN-wei
(School of chemistry and materials engineering,Liupanshui Normal University,Liupanshui,553004)
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投稿时间:2022-01-23     修订日期:2022-01-26     录用日期:2022-02-09     网络发布日期:2022-05-11
中文摘要: 铝灰中富含铝元素,具有极高的回收潜能。通过盐酸浸出分离铝灰中的铝,研究了初始酸浓度、浸出温度、时间、液固比等因素对铝灰中铝浸出率的影响。热力学分析发现,在pH小于2的酸性溶液中元素铝以Al3+形式存在。浸出试验结果表明,最优条件为:粒径-150 μm、温度80 ℃、初始酸浓度6 mol/L、液固比10、反应时间120 min,在此条件下Al浸出率可达85.86%。选择未反应收缩核模型进行浸出动力学分析,浸出过程受扩散控制,表观活化能为3.11 kJ/mol。通过提高反应温度、减小原料粒径、加强搅拌等方式可提升铝灰中铝浸出率。
Abstract:Aluminum dross is rich in aluminum and has high recovery potential. Effects of initial acid concentration, leaching temperature and time, and L/S on leaching rate of aluminum from aluminum dross were studied. Thermodynamic analysis shows that aluminum exists in the form of Al3+ in acidic solution when pH value is less than 2. Experimental results show that aluminum leaching rate is 85.86% under the optimum conditions including particle size of -150 μm, temperature of 80 ℃, initial acid concentration of 6 mol/L, L/S of 10, and reaction time of 120 min. The unreacted shrinking core model is used for leaching kinetic analysis. Leaching process is controlled by diffusion with apparent activation energy of 3.11 kJ/mol. Extraction rate of aluminum from aluminum dross can be improved by increasing reaction temperature, reducing raw material particle size, and strengthening stirring.
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基金项目:国家自然科学基金青年基金资助项目(51904150);贵州省科技计划项目(黔科合基础[2020]1Y225);贵州省普通高等学校科技拔尖人才项目(黔教合KY字[2019]056);六盘水市科技计划项目(52020-2019-05-09)
引用文本:
袁杰,罗亮昆,林安伟.铝灰酸浸提铝过程动力学研究[J].有色金属(冶炼部分),2022(6):37-42.
YUAN Jie,LUO Liang-kun,LIN AN-wei.Leaching Kinetics of Aluminum from Aluminum Dross with Hydrochloric Acid[J].Nonferrous Metals (Extractive Metallurgy),2022(6):37-42.

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