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有色金属(冶炼部分):2022,(5):26-31
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浓硫酸预活化—浸出高铅锌含砷烟尘
孙航宇, 杨洪英, 王志鹏, 张勤
(东北大学)
Concentrated Sulfuric Acid Pre-activation and Leaching of Arsenic Containing Dust with High-lead-zinc Content
SUN Hang-yu, YANG Hong-ying, WANG Zhi-peng, ZHANG Qin
(Northeastern University)
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投稿时间:2021-12-31     修订日期:2022-01-06     录用日期:2022-01-14     网络发布日期:2022-04-12
中文摘要: 针对铅冶炼产出的高铅锌含砷烟尘成分复杂、难于处理的特点,采用浓硫酸预活化—浸出处理工艺,进行铅、锌的回收以及砷、镉等有害元素的脱除。考察预活化及浸出过程中各参数对烟尘浸出过程的影响。研究表明:当酸尘比为1 mL/g、预活化温度60 ℃、预活化时间2 h、硫酸浓度0.5 mol/L、液固比5 mL/g、浸出温度80 ℃、浸出时间2 h,搅拌速度400 r/min时,效果最佳,锌、砷、镉、铅的浸出率分别为98.64%、95.02%、95.26%和0.16%。
中文关键词: 铅冶炼烟尘  预活化  浸出  锌  砷
Abstract:Aiming at complex and difficult-to-handle characteristics of high-lead-zinc containing arsenic dust from lead smelting furnace, a concentrated sulfuric acid pre-activation leaching process was used to recover lead and zinc and remove harmful elements such as arsenic and cadmium. Effects of various parameters in pre-activation and leaching process on leaching of fume were investigated. The results show that leaching rate of zinc, arsenic, cadmium, and lead is 98.64%, 95.02%, 95.26% and 0.16%, respectively under the optimum conditions including ratio of acid to dust of 1 mL/g, pre-activation temperature of 60 ℃, pre-activation time of 2 h, sulfuric acid concentration of 0.5 mol/L, L/S of 5 mL/g, leaching temperature of 80 ℃, leaching time of 2 h, and stirring speed of 400 r/min.
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基金项目:国家重点研发计划项目(2018YFC1902005)
引用文本:
孙航宇,杨洪英,王志鹏,张勤.浓硫酸预活化—浸出高铅锌含砷烟尘[J].有色金属(冶炼部分),2022(5):26-31.
SUN Hang-yu,YANG Hong-ying,WANG Zhi-peng,ZHANG Qin.Concentrated Sulfuric Acid Pre-activation and Leaching of Arsenic Containing Dust with High-lead-zinc Content[J].Nonferrous Metals (Extractive Metallurgy),2022(5):26-31.

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