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有色金属(冶炼部分):2022,(4):106-113
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镁钙铵系浸取剂对离子吸附型稀土矿区土壤生态影响初探
赵锦辉1, 赵龙胜2, 刘向生2, 齐少雷2, 刘德鹏2, 冯宗玉2
(1.北京科技大学冶金与生态工程学院;2.有研稀土新材料股份有限公司)
Preliminary Study on Ecological Impact of Leaching Agents Containing Mg2+, Ca2+, NH4+ on the Soil in Ion-adsorption Rare Earth Mining Area
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投稿时间:2021-11-20     修订日期:2021-11-24     录用日期:2021-11-29     网络发布日期:2022-03-15
中文摘要: 离子吸附型稀土矿富含宝贵的中重稀土战略资源,工业开采过程产生的氨氮污染问题长期备受关注。分别以硫酸镁、氯化钙和硫酸铵柱浸模拟离子吸附型稀土矿浸取尾矿,以中黄13大豆为供试作物,开展了室外盆栽试验,探究其对离子吸附型稀土矿区土壤的生态影响。结果表明,与采用铵浸尾矿种植相比,采用镁浸或钙浸尾矿种植的豆苗株高相当或更高,叶片的叶绿素含量更高或相当,根系生长正常,主根明显,侧根茂盛,且地径明显更粗,这可能与镁、钙等能直接参与叶绿素合成、加速糖分运输、改善土壤板结等有关。与采用硫酸铵浸取剂浸矿相比,采用硫酸镁、氯化钙浸取剂浸矿对离子吸附型稀土矿区土壤的生态影响更小,这也为离子吸附型稀土矿绿色开采和浸矿场地污染防治指明了发展方向。
Abstract:Ion-adsorption type rare earth ore is rich in valuable strategic resources of mid-heavy rare earths, and ammonia nitrogen pollution caused by its industrial mining process has long attracted attention. Column leaching using magnesium sulfate, calcium chloride and ammonium sulfate were employed to prepare simulated ion-adsorption rare earth tailings, and Zhonghuang 13 soybean was used as experimental crop. Outdoor pot experiments were conducted to explore ecological impact on the soil in ion-adsorption rare earth mining area. The results show that compared to soybean planted in ammonium-leached tailings, the soybeans planted in magnesium-leached or calcium-leached tailings grow quite or higher in plant height, chlorophyll content of their leaves is higher or equivalent, and their root system grows normally with obvious axial root and vigorous lateral roots. This may be attributed to the fact that magnesium and calcium can directly involve in synthesis of chlorophyll, accelerate transportation of sugar, and improve soil hardness. Leaching of ion-adsorption type rare earth ore using magnesium sulfate and calcium chloride has less ecological impact on the soil in mining area compared to that using ammonium sulfate. The development direction of green mining and pollution prevention for ion-adsorption rare earth mining area were pointed out.
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基金项目:国家自然科学基金重大研究计划资助项目(91962211);国家重点研发计划项目(2018YFC1801803)
引用文本:
赵锦辉,赵龙胜,刘向生,齐少雷,刘德鹏,冯宗玉.镁钙铵系浸取剂对离子吸附型稀土矿区土壤生态影响初探[J].有色金属(冶炼部分),2022(4):106-113.
ZHAO Jin-hui,ZHAO Long-sheng,LIU Xiang-sheng,QI Shao-lei,LIU De-peng,FENG Zong-yu.Preliminary Study on Ecological Impact of Leaching Agents Containing Mg2+, Ca2+, NH4+ on the Soil in Ion-adsorption Rare Earth Mining Area[J].Nonferrous Metals (Extractive Metallurgy),2022(4):106-113.

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