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投稿时间:2021-09-09 修订日期:2021-09-17 录用日期:2021-09-18 网络发布日期:2021-12-17
投稿时间:2021-09-09 修订日期:2021-09-17 录用日期:2021-09-18 网络发布日期:2021-12-17
中文摘要: 总结了近年来国内外废铅蓄电池回收的工艺特点,重点对铅膏湿法脱硫工艺及利用技术进行了综述,整体分为固-液、固-固两大脱硫技术体系,对比分析了现有技术特色与不足;从湿法预脱硫反应机理及其模型评述了湿法脱硫工艺的关键控制因素,探讨了脱硫过程中由产物层包覆引起的反应不彻底的问题;针对此问题,分析并且肯定了剪切、碰撞、研磨等机械强化方式对传质过程的促进作用,在此基础上,提出了边磨边浸出式强化脱硫的工艺发展方向。
Abstract:Technological characteristics of waste lead batterie recycling in recent years were briefly described from domestic and global aspect. Lead paste wet desulfurization process and utilization technology of current study were main summarized. The existing methods can be divided into solid-liquid and solid-solid desulfurization technology systems. Characteristics and shortcomings of the existing technologies were compared and analyzed. Key control factors of wet desulfurization process were reviewed from reaction mechanism and model of wet pre-desulfurization. The incomplete reaction caused by product layer coating during desulfurization process was discussed. In response to this problem, shear, collision, grinding and other mechanical strengthening methods were analyzed and confirmed due to their contribution of promoting mass transfer process. On this basis, outlook of grinding-leaching enhanced desulfurization was drawn.
文章编号: 中图分类号: 文献标志码:
基金项目:国家重点研发计划重点专项项目(2018YFC1903603)
| 作者 | 单位 | |
| 赵丽娟 | 北京工业大学 | zhaolj@emails.bjut.edu.cn |
| 谭哲 | 北京工业大学 | |
| 张晓光 | 北京工业大学 | |
| 吴广龙 | 生态环境部对外合作与交流中心 | |
| 潘军青 | 北京化工大学 | |
| 吴玉锋 | 北京工业大学 | |
| 潘德安* | 北京工业大学 | 15801662924@139.com |
引用文本:
赵丽娟,谭哲,张晓光,吴广龙,潘军青,吴玉锋,潘德安.废铅膏湿法脱硫工艺和利用技术研究进展[J].有色金属(冶炼部分),2022(1):118-126.
ZHAO Li-juan,TAN Zhe,ZHANG Xiao-guang,WU Guang-long,PAN Jun-qing,WU Yu-feng,Pan De-an.Research Progress of Wet Desulfurization Process and Utilization Technology of Waste Lead Paste[J].Nonferrous Metals (Extractive Metallurgy),2022(1):118-126.
赵丽娟,谭哲,张晓光,吴广龙,潘军青,吴玉锋,潘德安.废铅膏湿法脱硫工艺和利用技术研究进展[J].有色金属(冶炼部分),2022(1):118-126.
ZHAO Li-juan,TAN Zhe,ZHANG Xiao-guang,WU Guang-long,PAN Jun-qing,WU Yu-feng,Pan De-an.Research Progress of Wet Desulfurization Process and Utilization Technology of Waste Lead Paste[J].Nonferrous Metals (Extractive Metallurgy),2022(1):118-126.

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