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有色金属(冶炼部分):2021,(11):11-14
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硫酸锌溶液离子交换除氟氯工业化试验
邹维1, 杨大锦2, 刘俊场1, 曲洪涛2, 付维琴1, 付光2, 张特2, 卢文鹏2
(1.昆明冶金研究院有限公司;2.云南驰宏锌锗股份有限公司)
Industrial Test on Removal of Fluorine and Chlorine from Zinc Sulfate Solution with Ion Exchange
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投稿时间:2021-07-21     修订日期:2021-07-27     录用日期:2021-08-02     网络发布日期:2021-10-20
中文摘要: 开展了硫酸锌溶液离子交换除氟氯工业化试验,研究了吸附时间、解吸时间、解吸树脂pH等对硫酸锌溶液中氟氯脱除的影响。结果表明,在最佳工艺参数下,吸附过程氟、氯脱除率分别为61.47%和93.59%,解吸过程氟、氯解吸率分别为94.11%和97.50%,解吸液再生过程氟、氯挥发率分别为92.66%和98.66%。全流程溶液循环使用,减少了废水排放。
中文关键词: 硫酸锌溶液  氟  氯  离子交换  工业化试验
Abstract:Industrial experiment on removal of fluorine and chlorine ion from zinc sulfate solution by ion exchange was carried out. Effects of adsorption time, desorption time, and desorption resin pH value on removal of fluorine and chlorine from zinc sulfate solution were studied. The experimental results show that under the optimum process parameters, fluorine and chlorine removing rates is 61.47% and 93.59% respectively during adsorption process. In desorption process, fluorine and chlorine desorption rate is 94.11% and 97.50% respectively. In regeneration process, fluorine and chlorine volatilization rate is 92.66% and 98.66% respectively. The solution in whole process is recycled and waste water discharge is reduced.
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基金项目:云南省应用基础研究计划项目(202101AT070280);云南省转制科研院所技术开发研究专项(202104AR040007)
引用文本:
邹维,杨大锦,刘俊场,曲洪涛,付维琴,付光,张特,卢文鹏.硫酸锌溶液离子交换除氟氯工业化试验[J].有色金属(冶炼部分),2021(11):11-14.
ZOU Wei,YANG Da-jin,LIU Jun-chang,QU Hong-tao,FU Wei-qin,FU Guang,ZHANG Te,LU Wen-peng.Industrial Test on Removal of Fluorine and Chlorine from Zinc Sulfate Solution with Ion Exchange[J].Nonferrous Metals (Extractive Metallurgy),2021(11):11-14.

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