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有色金属(冶炼部分):2021,(11):79-84
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水热法制备V2O5作为高性能锂离子电池正极材料
(江西理工大学材料冶金化学学部)
Study on V2O5 Prepared by Hydrothermal Method as Cathode Material for High Performance Lithium-Ion Batteries
LI Ji-ming, LIU Jia-ming1,2, QIN Hui
(1.Faculty of Materials Metallurgy and Chemistry,Jiangxi University Science andTechnology;2.China)
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投稿时间:2021-07-14     修订日期:2021-08-01     录用日期:2021-08-02     网络发布日期:2021-10-20
中文摘要: 锂离子电池具有工作电压高、能量密度大等优点。目前,主流的正极材料如LiFePO4等存在理论容量低等问题,难以满足需求。V2O5具有层状结构,能够有效嵌锂,是一类新型的锂离子电池正极材料。但V2O5作为锂离子电池正极材料时循环稳定性较差,限制了其应用。采用水热法制备二维结构的V2O5纳米片材料,将其作为锂离子电池的正极材料,并与商业V2O5进行对比。测试表明,V2O5纳米片呈现片层状结构,粒径大小在130~280 nm,在循环伏安测试中有三对比较明显的氧化还原峰,经50次循环后V2O5纳米片可逆容量达到227 mAh/g,与第二圈的放电容量相比,容量保持率为89%,证明V2O5纳米片的储锂性能良好。
Abstract:Lithium-ion batteries have high working voltage and high energy density. At present, mainstream cathode materials such as LiFePO4 cannot meet the need due to its low theoretical capacity. V2O5 has a layered structure and can be effectively embedded with lithium. It is a new type of positive electrode for lithium-ion batteries. However, the poor cycle stability of V2O5 as a cathode material for lithium-ion batteries limits its application. V2O5 nanomaterials with two-dimensional structure were prepared by hydrothermal method and used as cathode materials for lithium-ion batteries, and compared with commercial V2O5. The results of a series of electrochemical tests show that lamellar structure of V2O5 is nanosheets with particle size of 130—280 nm; V2O5 nano sheet has three obvious redox peaks, which shows the process of three phase state transition of lithium ion embedded in V2O5 nano sheet. The cyclic stability test results show that after 50 cycles, reversible capacity of V2O5 nano sheet can still reach 227 mAh/g. Compared with discharge capacity of the second cycle, capacity retention rate is 89%, which proves that V2O5 nano chip has better lithium storage performance.
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基金项目:江西省大学生创新创业训练计划项目(S202010407012)
引用文本:
李基铭,刘嘉铭,覃慧.水热法制备V2O5作为高性能锂离子电池正极材料[J].有色金属(冶炼部分),2021(11):79-84.
LI Ji-ming,LIU Jia-ming,QIN Hui.Study on V2O5 Prepared by Hydrothermal Method as Cathode Material for High Performance Lithium-Ion Batteries[J].Nonferrous Metals (Extractive Metallurgy),2021(11):79-84.

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