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投稿时间:2021-04-12 修订日期:2021-04-22 录用日期:2021-04-25 网络发布日期:2021-06-21
投稿时间:2021-04-12 修订日期:2021-04-22 录用日期:2021-04-25 网络发布日期:2021-06-21
中文摘要: 以萍水河何雁桥至向阳湖段为研究对象,在21个采样点采集地表水样品,首先分析水体中10种重金属的空间污染特征,然后运用多元统计法对重金属间的相关性进行分析,最后采用USEPA推荐的健康风险评价模型评价重金属经饮水途径对成人和儿童产生的健康风险。结果表明,V、Fe、Mn的最大值均超过《地表水环境质量标准》(GB 3838—2002)Ⅲ类水质标准,最大超标2.3倍,重金属浓度均值大小依次为:Fe>Mn>V>Zn>Mo>As>Cu>Cd>Pb>Cr;从空间分布特征看,重金属多集中在研究区上游和下游,受人类工农业活动影响明显。Cu与Fe、Cu与Cr、Fe与Mn、As与V间呈现显著相关,相关系数分别为0.704、0.677、0.671和0.440,具有相同的来源或转换过程;Mo与Cu、Mo与Cr呈负显著相关,相关系数分别为-0.51、-0.44,表明来源不同或者两者间相互抑制。成人与儿童的健康总风险均大于最大可接受风险水平1.0×10-6,污染物致癌风险值比非致癌风险高3~4个数量级,总健康风险主要由Cr、As、Cd产生,儿童健康风险比成人健康风险高。模型参数的合理取值和本土化是精确量化地表水中重金属对人体健康影响的关键要素,特别对儿童进行健康风险评价应分年龄段计算。
Abstract:Taking section from Heyanqiao to Xiangyanghu of Pingshui River as research object, surface water samples were collected from the chosen 21 sampling points. Firstly, spatial pollution characteristics of 10 heavy metals in water body were analyzed, and then correlation between heavy metals was analyzed by multivariate statistical method, finally, health risk assessment model recommended by USEPA was used to evaluate health risk of heavy metals via route of water consumption for adults and children. The results show that the maximum values of V, Fe, and Mn all exceed the water quality standard of "Surface Water Environmental Quality Standard GB 3838—2002" Class Ⅲ with the maximum exceeding rate as high as 2.3 times, and heavy metals are listed in order according average concentrations: Fe>Mn>V>Zn>Mo>As>Cu>Cd>Pb>Cr. From perspective of spatial distribution characteristics, heavy metals are mostly concentrated in upstream and downstream of study area, which are significantly affected by human, industrial and agricultural activities. There are significant correlations between Cu and Fe, Cu and Cr, Fe and Mn, As and V, and their correlation coefficients are 0.704, 0.677, 0.671 and 0.440, respectively, it indicates that two of them have the same source or similar conversion process. Mo and Cu, Mo and Cr are negatively significantly correlated, and their correlation coefficients are -0.51 and -0.44, indicating that two of them may have different sources or mutual inhibition. Total health risks of adults and children are greater than the maximum acceptable risk level 1.0×10-6, and carcinogenic risk of pollutants is 3 to 4 orders of magnitude higher than the non-carcinogenic risk. Total health risks are mainly contributed by Cr, As, and Cd, and health risks of children are higher than adult. To accurately quantify impact on human health of heavy metals in surface water, reasonable values and localization of model parameters are the key elements, particularly children should be classified into different age groups to assess health risk. This research results can provide reference for research and prevention of heavy metal pollution in watershed.
keywords: heavy metal pollution characteristics health risk assessment multivariate statistics Pingshui River
文章编号: 中图分类号: 文献标志码:
基金项目:江西省自然科学基金重点项目(20181ACG70023;20181BAB213015)
引用文本:
章艳红,唐玉红,陈俊华,孙凯璇,武晋玄,刘斌.萍水河地表水重金属污染特征及健康风险评价[J].有色金属(冶炼部分),2021(7):116-125.
ZHANG Yan-hong,TANG Yu-hong,CHEN Jun-hua,SUN Kai-xuan,WU Jin-xuan,LIU Bin.Pollution Characteristics and Health Risk Assessment of Heavy Metals in Surface Water of Pingshui River[J].Nonferrous Metals (Extractive Metallurgy),2021(7):116-125.
章艳红,唐玉红,陈俊华,孙凯璇,武晋玄,刘斌.萍水河地表水重金属污染特征及健康风险评价[J].有色金属(冶炼部分),2021(7):116-125.
ZHANG Yan-hong,TANG Yu-hong,CHEN Jun-hua,SUN Kai-xuan,WU Jin-xuan,LIU Bin.Pollution Characteristics and Health Risk Assessment of Heavy Metals in Surface Water of Pingshui River[J].Nonferrous Metals (Extractive Metallurgy),2021(7):116-125.

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