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有色金属(冶炼部分):2021,(7):42-48
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超声波对硫代硫酸盐浸金体系稳定性的影响
邓卓, 李齐, 陈俊南, 谢锋, 畅永锋, 王伟
(东北大学冶金学院)
Effect of Ultrasound on Copper Ammonia Thiosulfate Gold Leaching System
DENG Zhuo, LI Qi, CHEN Jun-nan, XIE Feng, CHANG Yong-feng, WANG Wei
(School of Metallurgy, Northeastern University)
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投稿时间:2021-03-15     修订日期:2021-03-22     录用日期:2021-03-28     网络发布日期:2021-06-21
中文摘要: 探索了超声波作用对铜氨硫代硫酸钠浸金体系稳定性的影响。考察了不同浸出时间、温度、超声波功率、pH和氨水浓度条件下,浸金体系内硫代硫酸根离子浓度以及Cu(NH3)42+络合离子浓度变化规律。结果表明,超声波作用使硫代硫酸盐浸金体系稳定性有所降低,一定条件下可显著促进硫代硫酸根离子和Cu(NH3)42+络合离子浓度的降低。金矿石浸出试验表明,当Na2S2O3浓度为0.1 mol/L、CuSO4浓度为0.03 mol/L、NH3?H2O浓度为0.45 mol/L时,超声波作用能够显著提高浸金率,在较低浸出温度下引入超声波辅助浸出就能达到常规较高温度下的浸出效果。本研究为降低硫代硫酸盐浸金反应的温度开辟了新的路径。
中文关键词: 硫代硫酸盐  浸金  超声波  稳定性
Abstract:Effect of ultrasound on stability of copper ammonia sodium thiosulfate leaching gold system was explored. Changes of thiosulfate ion concentration and Cu(NH3)42+ complex ion concentration in gold leaching system under different conditions of leaching time, temperature, ultrasonic power, pH value and ammonia concentration were investigated. The results show that ultrasonic effect reduces stability of thiosulfate gold leaching system, and can significantly promote decomposition of thiosulfate ion and Cu(NH3)42+ complex ion concentration under certain conditions. Gold ore leaching test shows that when concentration of Na2S2O3 is 0.1 mol/L, concentration of CuSO4 is 0.03 mol/L, and concentration of NH3?H2O is 0.45 mol/L, ultrasonic effect can significantly increase gold leaching rate. and it is introduced. With aid of ultrasound, conventional higher temperature leaching effect can be achieved at lower temperature. This study opens a new research path for reducing temperature of thiosulfate leaching gold reaction.
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基金项目:国家自然科学基金资助项目(U1702252)
引用文本:
邓卓,李齐,陈俊南,谢锋,畅永锋,王伟.超声波对硫代硫酸盐浸金体系稳定性的影响[J].有色金属(冶炼部分),2021(7):42-48.
DENG Zhuo,LI Qi,CHEN Jun-nan,XIE Feng,CHANG Yong-feng,WANG Wei.Effect of Ultrasound on Copper Ammonia Thiosulfate Gold Leaching System[J].Nonferrous Metals (Extractive Metallurgy),2021(7):42-48.

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