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有色金属(冶炼部分):2021,(7):55-61
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废弃液晶面板中有机热解炭还原回收铟的研究
(上海第二工业大学电子废弃物研究中心)
Study on Recovery of Indium from Waste Liquid Crystal Panels by Organic Pyrolytic Carbon Reduction
WANG Yan-ping1, WANG Rui-xue2, ZHANG Cheng-long, MA En, WANG Jing-wei
(1.WEEE Research Centre of Shanghai Polytechnic University;2.Shanghai Polytechnic University)
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投稿时间:2021-03-11     修订日期:2021-03-17     录用日期:2021-03-22     网络发布日期:2021-06-21
中文摘要: 废弃液晶面板(LCD)中铟的回收是缓解铟资源供求矛盾、消除废弃LCD环境污染的重要途径。以废弃LCD中有机材料的热解产物为还原剂,在高温、高真空条件下回收废弃LCD玻璃基板中的铟。利用氮气热解处理废弃LCD中的有机组分,并利用响应曲面法进行参数优化,优化条件下(温度350 ℃、升温速率2 ℃/min、N2流速0.36 L/min)热解炭产率可达28.68%;将热解炭作为还原剂回收玻璃基板中的铟,较优条件(温度935 ℃,压力1 Pa,碳添加量40%,反应时间0.5 h)下铟转化率可达99.63%。将“废渣”转化为“反应原料(还原剂)”,同时将“有机物去除”和“铟提取”两个过程有机结合,在去除有机污染物的同时也完成了金属铟的资源回收,可为绿色、高效的回收废弃LCD提供理论基础和实践经验。
Abstract:Recycling of indium (In) from waste liquid crystal displays (LCD) is quite important to solve indium resource shortage and waste LCD pollution. Pyrolysis products of organic matters from waste LCD were used as reductant to recover indium under high temperature/vacuum conditions. Organic matter of waste LCD panels was treated with nitrogen pyrolysis, and parameters were optimized by response surface methodology. Pyrolytic carbon productivity is 28.68% under the optimum conditions including temperature of 350 ℃, heating rate of 2 ℃/min, and N2 flow rate of 0.36 L/min. Indium conversion rate from waste LCD panels is 99.63% under the optimum conditions including temperature of 935 ℃, pressure of 1 Pa, mass fraction of pyrolytic carbon dosage of 40%, and reaction time of 0.5 h. “Waste residue” can be transformed into “reaction raw material (reductant)”, and “organics removal stage” is integrated with “indium recycling stage” in closed-loop management system, as a result, organic pollutants are settled with indium resource recovery at the same time. This program can simplify process route of waste LCD recycling, and provide fundamental basis as well as practical experience for recycling waste LCD environmentally and efficiently.
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基金项目:国家自然科学基金资助项目(21806102);上海市青年科技英才扬帆计划资助项目(18YF1408800);国家重点研发计划项目(2018YFC1902300);上海第二工业大学研究生基金资助项目(No.EGD19YJ0001)
引用文本:
王燕萍,王瑞雪,张承龙,马恩,王景伟.废弃液晶面板中有机热解炭还原回收铟的研究[J].有色金属(冶炼部分),2021(7):55-61.
WANG Yan-ping,WANG Rui-xue,ZHANG Cheng-long,MA En,WANG Jing-wei.Study on Recovery of Indium from Waste Liquid Crystal Panels by Organic Pyrolytic Carbon Reduction[J].Nonferrous Metals (Extractive Metallurgy),2021(7):55-61.

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