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有色金属(冶炼部分):2021,(6):18-24
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刚果(金)某氧化铜精矿还原熔炼渣物化性能研究
苏凤来1, 杨必文2, 张登高2, 郑朝振2
(1.紫金矿业集团穆索诺伊矿业简易股份有限公司;2.矿冶科技集团有限公司)
Research on Physical and Chemical Properties of Reduction Smelting Slag of a Copper Oxide Concentrate in Democratic Republic of Congo
SU Feng-lai1, YANG Bi-wen, ZHANG Deng-gao, ZHENG Chao-zhen2
(1.Zijin Mining Group COMMUS SAS Kolowezi;2.BGRIMM Technology Group,Beijing)
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投稿时间:2020-12-25     修订日期:2020-12-31     录用日期:2021-01-04     网络发布日期:2021-05-20
中文摘要: 针对刚果(金)某氧化铜精矿中高硅、低铁的特性,通过高温马弗炉还原熔炼试验,考察了碱度和FeO对熔渣形貌、熔点、密度、黏度及电导率的影响。结果表明,该体系熔渣主要以硅酸钙的玻璃相存在,Mg、Al及Fe分散在其中。随着碱度从0.2增加到0.6,熔渣熔点先降低后升高,黏度先增大后减小,密度先减少后增大,电导率呈上升趋势;随着FeO含量从6%增加到10%,熔渣熔点和黏度呈下降趋势,密度和电导率呈上升趋势。适合本体系熔渣的碱度为0.5左右,FeO加入量<6%。则熔渣熔化温度<1 250 ℃,黏度<2 Pa?s(1 400 ℃),密度2.6~3.0 g/cm3。此时,粗铜品位达到96.5%,铜收得率超过98%。
Abstract:Based on characteristics of high-silicon and low-iron content in a copper oxide concentrate, influence of basicity and FeO content on slag morphology, melting point, density, viscosity and electrical conductivity was investigated by reduction melting experiment in a high-temperature muffle furnace. The results show that this system slag mainly exists in glassy phase of calcium silicate, with Mg, Al and Fe dispersed in it. With increase of basicity from 0.2 to 0.6, melting point and density of slag drop first and rise later, viscosity rises first and drops later, and conductivity shows an rising trend. However, with increase of FeO content from 6% to 10%, melting point and viscosity of slag show a dropping trend, and density and conductivity show a rising trend. The suitable basicity of this system slag is about 0.5, and FeO addition should be less than 6%. Melting temperature is of <1 250 ℃, viscosity is of <2 Pa?s (1 400 ℃), and density is of 2.6~3.0 g/cm3. Thus, grade of crude copper is 96.5% with copper yield of 98% above.
文章编号:     中图分类号:    文献标志码:
基金项目:国家重点研发计划项目(2018YFC1900303)
引用文本:
苏凤来,杨必文,张登高,郑朝振.刚果(金)某氧化铜精矿还原熔炼渣物化性能研究[J].有色金属(冶炼部分),2021(6):18-24.
SU Feng-lai,YANG Bi-wen,ZHANG Deng-gao,ZHENG Chao-zhen.Research on Physical and Chemical Properties of Reduction Smelting Slag of a Copper Oxide Concentrate in Democratic Republic of Congo[J].Nonferrous Metals (Extractive Metallurgy),2021(6):18-24.

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