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有色金属(冶炼部分):2020,(11):79-84
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硫酸锰溶液深度除重金属制备电池级硫酸锰
王岳俊1, 王维娜1, 刘易伦1, 刘芬2, 陈星宇2
(1.河套学院 生态与资源工程系;2.中南大学 冶金与环境学院)
Removal of Heavy Metals from Manganese Sulfate Solution and Preparation of Battery-level Manganese Sulfate
WANG Yue-jun1, WANG wei-na, LIU Yi-lun, LIU Fen, CHEN Xing-yu2
(1.(1. Department of Ecology and Resources Engineering, Hetao College;2.School of Metallurgy and Environment, Central South University)
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投稿时间:2020-08-09     修订日期:2020-08-16     录用日期:2020-08-17     网络发布日期:2020-10-31
中文摘要: 随着电池行业对硫酸锰产品质量要求日趋严格,硫酸锰生产过程中的除杂要求也逐渐提高。采用不同形态MnS对工业级硫酸锰进行重金属的净化除杂。采用控制变量法,分别考察了反应温度、时间、pH和新生态MnS用量对除杂效果的影响。结果表明,新生态MnS的除杂效果优于粉末态MnS,最佳条件为:新生态MnS加入量6 g/L、反应pH=3.6、反应温度80 ℃、反应时间1.5 h,在此条件下,净化液中Fe、Cu、Zn、Pb的含量分别为0.3、0、0.3、6.5 μg/L,达到电池级硫酸锰的产品质量标准。
Abstract:With strict requirement of battery industry for quality of manganese sulfate products, purification of manganese sulfate during production improves gradually. Effects of different forms of MnS on purification and removal of heavy metals in industrial grade manganese sulfate were compared. Effects of reaction temperature, reaction time, pH value and amount of new ecological MnS on purification were investigated by control variable method. The results show that new ecological MnS is better than powdered MnS. The optimum conditions of purification with new ecological MnS include dosage of new ecological MnS of 6 g/L, pH value of 3.6, reaction temperature of 80 ℃, and reaction time of 1.5 h, under these conditions, content of Fe, Cu, Zn and Pb in manganese sulfate solution is 0.3, 0, 0.3, and 6.5 μg/L, which meet the standards of battery-level manganese sulfate.
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基金项目:国家自然科学基金地区基金资助项目(51664013);内蒙古自治区高等学校“青年科技英才支持计划”项目(NJYT-17-B35);巴彦淖尔科技计划项目(K201509)
引用文本:
王岳俊,王维娜,刘易伦,刘芬,陈星宇.硫酸锰溶液深度除重金属制备电池级硫酸锰[J].有色金属(冶炼部分),2020(11):79-84.
WANG Yue-jun,WANG wei-na,LIU Yi-lun,LIU Fen,CHEN Xing-yu.Removal of Heavy Metals from Manganese Sulfate Solution and Preparation of Battery-level Manganese Sulfate[J].Nonferrous Metals (Extractive Metallurgy),2020(11):79-84.

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