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投稿时间:2020-05-20 修订日期:2020-05-22 录用日期:2020-05-26 网络发布日期:2020-07-17
投稿时间:2020-05-20 修订日期:2020-05-22 录用日期:2020-05-26 网络发布日期:2020-07-17
中文摘要: 研究了草酸反萃并直接沉淀负载富钇的P507有机相中富钇的工艺参数,考察了草酸反萃富钇过程中草酸用量、反萃温度、反萃相比O/A、反萃时间、反萃级数对稀土反萃率的影响。结果表明,草酸反萃最佳的工艺参数为:草酸用量为理论值的130%、反萃温度25 ℃、O/A=1/1、反萃时间20 min、反萃级数11级,在此条件下,富钇稀土反萃率为99.45%,所得富钇产品质量为TREO>98.0%、Cl-<0.05%、残碳0.042%。
Abstract:Process parameters of oxalic acid stripping and direct precipitation loading of yttrium-rich P507 organic phase were studied. Effects of oxalic acid dosage, stripping temperature, O/A ratio, stripping time, and stripping series on RE stripping rate were investigated. The results show that stripping rate of yttrium-rich rare earth is 99.45 % and TREO in yttrium-rich product is 98.0% above with Cl-<0.05% and residual carbon of 0.042% under the optimum conditions including oxalic acid dosage of 130% of theoretical value, stripping temperature of 20 ℃, O/A=1/1, stripping time of 20 min, and stripping series of 11.
keywords: yttrium-rich oxalic acid stripping precipitation P507
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基金项目:国家科技部转制科研院所创新能力专项(2014EG115016);赣州市产学研合作科技创新重点项目(赣市财教字[2016]15号);赣州市科技创新人才计划项目(赣市科发[2018]50号)
| 作者 | 单位 | |
| 伍莺 | 赣州有色冶金研究所 | 262748791@qq.com |
| 周洁英 | 赣州有色冶金研究所 | |
| 胡小洣 | 赣州有色冶金研究所 | |
| 张积锴 | 赣州有色冶金研究所 | |
| 陈冬英* | 赣州有色冶金研究所 | 13970799704@163.com |
引用文本:
伍莺,周洁英,胡小洣,张积锴,陈冬英.草酸反萃沉淀法从负载钇的P507中提取富钇[J].有色金属(冶炼部分),2020(8):68-71.
WU Ying,ZHOU Jie-ying,HU Xiaomi,ZHANG Ji-kai,CHAN dong-ying.Extraction of Yttrium-rich from P507 Loaded with Yttrium by Oxalic Acid Stripping[J].Nonferrous Metals (Extractive Metallurgy),2020(8):68-71.
伍莺,周洁英,胡小洣,张积锴,陈冬英.草酸反萃沉淀法从负载钇的P507中提取富钇[J].有色金属(冶炼部分),2020(8):68-71.
WU Ying,ZHOU Jie-ying,HU Xiaomi,ZHANG Ji-kai,CHAN dong-ying.Extraction of Yttrium-rich from P507 Loaded with Yttrium by Oxalic Acid Stripping[J].Nonferrous Metals (Extractive Metallurgy),2020(8):68-71.

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