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有色金属(冶炼部分):2020,(9):88-96
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耐氰碳酸盐矿化菌的筛选及原位固化氰化尾渣研究
王维大, 武永明, 李硕, 王哲, 姜庆宏, 郑春丽
(内蒙古科技大学能源与环境学院)
Screening of Cyanide-resistant Carbonate Mineralizing Bacteria and Study on Its Solidifying Effect of Cyanide Tail Residue
WANG Wei-da, WU Yong-ming, LI Shuo, WANG Zhe, JIANG Qing-hong, ZHENG Chun-li
(School of Energy and Environment,Inner Mongolia University of Science and Technology)
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投稿时间:2020-03-02     修订日期:2020-03-09     录用日期:2020-03-10     网络发布日期:2020-08-17
中文摘要: 从某含氰金矿尾渣中分离筛选得到一株高效矿化菌,经16S rDNA鉴定为芽孢杆菌(Bacillus.sp),将其命名为JK-2。进行了JK-2诱导碳酸钙沉淀固化含氰金矿尾渣中重金属的研究,考察微生物诱导碳酸钙沉淀(MICP)过程后尾矿的固化效果及对重金属的固定率,同时利用SEM、XRD、FT-IR等表征分析MICP过程的产物。结果表明:JK-2能有效固化金矿尾渣,随着黏结液浓度的增加,固化后固化体的无侧限抗压强度增大,最高可达0.72 MPa。此外,固定金矿尾渣中易迁移态的重金属铅向碳酸盐结合态转化;尾矿中铅、铬的固定率分别达88.7%、63.5%;SEM显示固化后有大量的晶体形成,FT-IR图谱显示,固化产物中有CO32-存在,经XRD测定,固化产物主要为方解石和球霰石。
中文关键词: 产脲酶菌  MICP  金矿尾渣  氰化物  重金属
Abstract:One highly efficient mineralized bacterium was isolated and screened from tailing slag of cyanide-bearing gold mine, which was identified as bacillus.sp by 16S rDNA and named JK-2. Heavy metals in gold tailings were solidified by JK-2 induced precipitation of calcium carbonate. Solidification effect of tailings after MICP process and heavy metal fixation rate were investigated. Products of MICP process were analyzed by SEM, XRD, FT-IR and other characterization methods. The results show that JK-2 can effectively solidify gold mine tailings, and unconfined compressive strength of cured body rises with increase of binder concentration, which the highest is up to 0.72 MPa. Lead in fixed gold tailings is transformed into carbonate binding state. Fixed rate of Pb and Cr in tailings is 88.7% and 63.5% respectively. SEM shows that a large number of crystals are formed after curing, and FT-IR spectrum shows that CO32- exists in solidified products. According to XRD, solidification products are mainly calcite and spherical aragonite.
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基金项目:国家重点研发计划项目(2018YFC1802904);内蒙古自然科学基金青年基金资助项目(2016BS0511);内蒙古科技大学创新基金项目(2016QDL-B08)
引用文本:
王维大,武永明,李硕,王哲,姜庆宏,郑春丽.耐氰碳酸盐矿化菌的筛选及原位固化氰化尾渣研究[J].有色金属(冶炼部分),2020(9):88-96.
WANG Wei-da,WU Yong-ming,LI Shuo,WANG Zhe,JIANG Qing-hong,ZHENG Chun-li.Screening of Cyanide-resistant Carbonate Mineralizing Bacteria and Study on Its Solidifying Effect of Cyanide Tail Residue[J].Nonferrous Metals (Extractive Metallurgy),2020(9):88-96.

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