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投稿时间:2019-09-29 修订日期:2019-10-06 录用日期:2019-10-07 网络发布日期:2020-02-17
投稿时间:2019-09-29 修订日期:2019-10-06 录用日期:2019-10-07 网络发布日期:2020-02-17
中文摘要: 以某盐湖提钾后老卤为研究对象,其中锂含量仅有0.15 g/L,镁锂比达到800︰1。磁性铝系吸附剂的饱和吸附容量为4.3 mg/g,提锂后吸附剂利用超导磁选机实现与卤水的固液分离,同步实现洗盐和解吸,最终得到含锂解吸液产品。研究表明,超导磁选机采用钢网片聚磁介质,背景磁场强度2 400 kA/m,吸附剂浓度10%,下料速度10 cm/s的情况下,吸附剂的截留率达到99%以上。在500 mL淡水洗盐,1.5 L淡水解吸,解吸液中Li+ 0.28 g/L,Mg2+0.57 g/L,全流程卤水中锂的回收率在80%以上;吸附剂在磁选机进行100次吸附解吸循环,吸附剂累计丢失8.9%。该工艺有一定的工业利用价值。
Abstract:Old brine with Li+ 0.15 g/L and Mg2+ 119.5 g/L after potassium extraction from a salt lake was researched. Saturated adsorption capacity of magnetic aluminum-based adsorbent is 4.3 mg/g. Separation of adsorbent from brine was carried out by superconducting magnetic separator to realize synchronization salt leaching and desorption. Final product is lithium-bearing stripping solution. The results show that retention rate of adsorbent is 99% above under the conditions including superconducting magnetic separator adopting steel mesh medium, background magnetic field strength of 2 400 kA/m, adsorbent concentration of 10%, and feeding speed of 10 cm/s. Recovery rate of lithium from brine in whole process is 80% above under the conditions including salt leaching with 500 mL fresh water, desorption with 1.5 L fresh water, and concentration of Li+ and Mg2+ in desorption solution of 0.28 g/L and 0.57 g/L respectively. Lost of adsorbent is 8.9% after 100 adsorption desorption cycles in magnetic separation system. This process has certain industrial value in practice.
文章编号: 中图分类号: 文献标志码:
基金项目:国家自然科学基金资助项目(41867021);江西省自然科学基金资助项目(20171BAB206048)
| 作者 | 单位 | |
| 张凯 | 东华理工大学 | mouseulll@163.com |
| 李亦然* | 江西省南昌市青山湖区广兰大道418号东华理工大学 | liyiran@ecut.cn |
| 马君耀 | 江苏旌凯中科超导高技术有限公司 | |
| 侯愷 | 江西省南昌市青山湖区广兰大道418号东华理工大学 |
| Author Name | Affiliation | |
| ZHANG Kai | East China University of Technology | mouseulll@163.com |
| LI Yi-ran | liyiran@ecut.cn | |
| MA Jun-yao | ||
| HOU Kai |
引用文本:
张凯,李亦然,马君耀,侯愷.超导磁吸附卤水提锂研究[J].有色金属(冶炼部分),2020(3):32-37.
ZHANG Kai,LI Yi-ran,MA Jun-yao,HOU Kai.Study on Lithium Extraction from Brine by Superconducting Magnetic Separation and Adsorption[J].Nonferrous Metals (Extractive Metallurgy),2020(3):32-37.
张凯,李亦然,马君耀,侯愷.超导磁吸附卤水提锂研究[J].有色金属(冶炼部分),2020(3):32-37.
ZHANG Kai,LI Yi-ran,MA Jun-yao,HOU Kai.Study on Lithium Extraction from Brine by Superconducting Magnetic Separation and Adsorption[J].Nonferrous Metals (Extractive Metallurgy),2020(3):32-37.

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