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有色金属(冶炼部分):2019,(1):42-47
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砂岩铀矿CO2+O2地浸初期流场模拟及水化学验证
周义朋,黎广荣,徐玲玲,孙占学,周仲魁,李衡
(核资源与环境国家重点实验室,核资源与环境国家重点实验室,核资源与环境国家重点实验室,核资源与环境国家重点实验室,核资源与环境国家重点实验室,核资源与环境国家重点实验室)
Flow Field Simulation and Hydrochemical Verification from CO2+O2 In-situ Leaching of Sandstone-type Uranium Deposit
Zhou Yipeng,Li Guangrong,Xu Lingling,Sun Zhanxue,Zhou Zhongkui and Li Heng
(State Key Laboratory of Nuclear Resources and Environment,East China Institute of Technology,,,,,)
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投稿时间:2018-11-20     修订日期:2018-11-20     录用日期:2018-11-21     网络发布日期:2018-12-21
中文摘要: 以新疆某砂岩型铀矿床“六注两抽”的地浸单元为研究对象,采用数值模拟与水化学分析相结合的方法,对CO2+O2中性地浸初期流场形成进程及其与溶质运移的关系进行了研究。结果表明,在以抽孔和注孔连线为轴线的纺锤形地浸流场中,地浸溶液前锋用时15 d抵达抽液孔。SO42-和HCO3-浓度变化对地浸初期前锋溶液渗流的反应灵敏而精准,是判断CO2+O2中性地浸最初阶段溶液前锋运移理想的天然示踪剂。地浸初期Ca2+、Mg2+的碳酸盐都处于过饱和状态,其运移滞后于溶液渗流并与pH的变化密切同步。渗流模拟、水文地球化学模式计算结果以及实际水化学监测数据之间存在良好的互证性,这些方法的综合应用可使地浸流场分析更为客观和可靠。
Abstract:Taking “six-injection and two-pumping” in-situ leaching units in a sandstone-type uranium deposit in Xinjiang as research object, applying combination of numerical simulation and hydrochemical analysis to form initial flow field of CO2+O2 neutral leaching and its relationship with solute transport was studied. The results show that in spindle-shaped flow field with axis of injection-pumping holes, solution front reaches the pregnant holes within 15 days; and concentration changes of SO42- and HCO3- are sensitive and accurate for infiltration of the forward solution of in-situ leaching. It is an ideal tracer for judging the forward flow of solution in initial stage of CO2+O2 neutral leaching. Initial calcium and magnesium carbonates are both in supersaturated state, and their migrations lag behind solution infiltration and is closely synchronized with change in pH value. There is good mutual proof between calculation results of leaching simulation, hydrogeochemical model and actual water chemical monitoring data. The comprehensive application of these methods is more objective and reliable in analysis of in-situ leaching flow field.
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基金项目:国家自然科学基金资助项目(41572231);国家重点基础研究发展计划(973计划)项目(2015CB453002);江西省科技计划项目(20142BFB29004,20151BBB60093)
引用文本:
周义朋,黎广荣,徐玲玲,孙占学,周仲魁,李衡.砂岩铀矿CO2+O2地浸初期流场模拟及水化学验证[J].有色金属(冶炼部分),2019(1):42-47.
Zhou Yipeng,Li Guangrong,Xu Lingling,Sun Zhanxue,Zhou Zhongkui,Li Heng.Flow Field Simulation and Hydrochemical Verification from CO2+O2 In-situ Leaching of Sandstone-type Uranium Deposit[J].Nonferrous Metals (Extractive Metallurgy),2019(1):42-47.

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