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有色金属(冶炼部分):2019,(1):68-72
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钢渣负载羟基磷灰石复合材料对水溶液中铀的去除性能
莫京倚,张卫民,郭亚丹,钱程,覃海富,杨天梓,昝金晶,曾华
(东华理工大学,东华理工大学,东华理工大学,东华理工大学,东华理工大学,东华理工大学,东华理工大学,东华理工大学)
Removal of Uranium from Aqueous Solution by Steel Slag Loaded with Hydroxyapatite
Mo jing yi,zhang wei min,guo ya dan,QIAN Cheng,QIN Hai fu,YANG Tian zi,ZAN Jin jing and ZENG hua
(East China University of Technology,,,,,,,)
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投稿时间:2018-10-14     修订日期:2018-10-17     录用日期:2018-10-22     网络发布日期:2018-12-21
中文摘要: 采用溶胶—凝胶法制备出钢渣负载羟基磷灰石复合材料,并通过静态试验方法探讨pH、复合材料投加量、反应时间及铀初始浓度对复合材料吸附水溶液中U(Ⅵ)的影响。结果表明,复合材料对U(Ⅵ)具有较好的去除性能,在pH=4、投加量0.4 g、反应时间120 min的条件下,对初始浓度5 mg/L的水溶液中U(Ⅵ)的去除接近完全,对应吸附量为1.25 mg/g。复合材料对U(Ⅵ)的吸附过程为化学吸附,符合准二级动力学模型(R2=0.996 9);Langmuir吸附等温线模型拟合(R2=0.999 1)表明,吸附过程为吸附剂表面上的单层吸附;且通过RL(RL<0.063)的计算表明,复合材料对U(Ⅵ)的吸附极其接近不可逆吸附。
Abstract:Composite material of steel slag loaded with hydroxyapatite was prepared by sol-gel method with steel slag as carrier. Effects of pH value, adsorbent dosage, reaction time and initial uranium concentration on adsorption of U(VI) in aqueous solution were investigated by static test. The results show that this material has better removal property of U(VI). The results show that removal rate of U (VI) in aqueous solution with initial concentration of 5 mg/L is nearly 100% with adsorption capacity of 1.25 mg/g under the conditions of pH=4, dosage of 0.4 g and reaction time of 120 min. Adsorption process of U(VI) on composite is chemical adsorption which is more in line with quasi-second-order kinetic model (R2=0.996 9). Langmuir adsorption isotherm model (R2=0.999 1) shows that adsorption process is monolayer adsorption on surface of adsorbent, and the RL (RL<0.063) calculation shows that adsorption of U (VI) on composite is very close to irreversible adsorption.
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基金项目:国家自然科学基金资助项目(41562011);江西省教育厅科技计划项目(GJJ150577)
引用文本:
莫京倚,张卫民,郭亚丹,钱程,覃海富,杨天梓,昝金晶,曾华.钢渣负载羟基磷灰石复合材料对水溶液中铀的去除性能[J].有色金属(冶炼部分),2019(1):68-72.
Mo jing yi,zhang wei min,guo ya dan,QIAN Cheng,QIN Hai fu,YANG Tian zi,ZAN Jin jing,ZENG hua.Removal of Uranium from Aqueous Solution by Steel Slag Loaded with Hydroxyapatite[J].Nonferrous Metals (Extractive Metallurgy),2019(1):68-72.

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