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投稿时间：2018-02-01 修订日期：2018-02-01 录用日期：2018-02-05 网络发布日期：2018-06-15
投稿时间：2018-02-01 修订日期：2018-02-01 录用日期：2018-02-05 网络发布日期：2018-06-15
中文摘要: 采用移动密实床离子交换柱吸附—固定床离子交换柱解吸—蒸发冷却结晶等工序进行高温合金电溶液中铼的高效回收工业试验。结果表明，采用移动密实床交换柱吸附—固定床离子交换柱解吸和再生，可使整个离子交换系统连续运行；采用15BVs 8%NH4SCN溶液解吸铼时，可使流出液含铼浓度降至1 mg/L；采用20BVs 2 mol/L H2SO4溶液使树脂再生时，再生树脂对铼吸附率仍可达99.97%，且吸附后液含铼浓度可降至0.4 mg/L；采用6倍理论用量CaCl2沉钼时，钼沉淀率为99.69%；最终所得铼酸铵产品纯度达到99.99%。
Abstract:Industrial test to recover Re from electrolytic solution of superalloy was performed by moving-dense-bed column adsorption, fixed-bed column desorption, and evaporative cooling crystallization. The results show that the entire ion-exchange system can be continuously operated by moving-dense-bed column adsorption, fixed-bed column desorption and regeneration. Rhenium concentration in effluent drops to 1 mg/L applying 15BVs 8%NH4SCN solution to desorb Re. Rhenium adsorption rate of regenerated resin is 99.97% and Re concentration in adsorbed solution drops to 0.4 mg/L after loaded resin regenerated with 20BVs 2 mo/L H2SO4 solution. Mo precipitation rate is 99.69% applying 6 times of theoretical amount of CaCl2 to precipitate Mo. Purity of ammonium rhenate product is 99.99%.
文章编号： 中图分类号：TF841.8 文献标志码：
基金项目:西安市未央区科技计划项目(201704)
| 作者 | 单位 | |
| 陈昆昆* | 西北有色金属研究院 | chenk_007@163.com |
| 许万祥 | 西安瑞鑫科金属材料有限责任公司 | |
| 郭瑞 | 西安瑞鑫科金属材料有限责任公司 | |
| 操齐高 | 西北有色金属研究院 |
| Author Name | Affiliation | |
| CHEN Kun-kun | Northwest Institute for Non-ferrous Metal Research,Xi’an | chenk_007@163.com |
| XU Wan-xiang | ||
| GUO Rui | ||
| CAO Qi-gao |
引用文本：
陈昆昆,许万祥,郭瑞,操齐高.从高温合金电溶液中回收铼酸铵的工业试验[J].有色金属（冶炼部分）,2018(7):31-34.
CHEN Kun-kun,XU Wan-xiang,GUO Rui,CAO Qi-gao.Industrial Test to Recover Ammonium Rhenate from Electrolytic Solution of Superalloy[J].Nonferrous Metals (Extractive Metallurgy),2018(7):31-34.
陈昆昆,许万祥,郭瑞,操齐高.从高温合金电溶液中回收铼酸铵的工业试验[J].有色金属（冶炼部分）,2018(7):31-34.
CHEN Kun-kun,XU Wan-xiang,GUO Rui,CAO Qi-gao.Industrial Test to Recover Ammonium Rhenate from Electrolytic Solution of Superalloy[J].Nonferrous Metals (Extractive Metallurgy),2018(7):31-34.
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