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投稿时间:2017-04-05 修订日期:2017-04-20 录用日期:2017-04-21 网络发布日期:2017-08-21
投稿时间:2017-04-05 修订日期:2017-04-20 录用日期:2017-04-21 网络发布日期:2017-08-21
中文摘要: 在1 000~1 300 ℃添加少量Na2CO3 NaCl复配添加剂,以无烟煤做还原剂等温还原低品位钒钛磁铁精矿,再通过磁选分离获得铁精粉和钒钛渣。考察了C/Fe摩尔比、还原温度和还原时间对铁的还原、钒钛迁移富集行为以及物相转化规律的影响。结果表明,C/Fe摩尔比和反应温度对直接还原过程中有价组分迁移富集的影响很大,当C/Fe摩尔比为1.2时,在1 200 ℃还原2 h,钒钛磁铁矿精矿的金属化率可达到92.8%,还原后钒主要富集在钛渣相中,有效实现了铁与钒/钛的分离。
Abstract:Low grade vanadium-bearing titanomagnetite concentrates were reduced isothermally with addition of a small amount of Na2CO3 NaCl at 1 000~1 300 ℃ and anthracite as reductant. Iron concentrates and vanadium-bearing titanium slag were obtained by magnetic separation. The effects of C/Fe molar ratio, reduction temperature, and reduction time on metallization degree of iron, content of V/Ti in samples, and phase transformation were investigated. The results show that C/Fe molar ratio and reduction temperature have great impacts on direct reduction process. Metallization degree is 92.8% under the conditions including C/Fe molar ratio of 1.2, reduction temperature of 1 200 ℃, and reduction time of 2 h. Vanadium is enriched in titanium slag after reduction. Efficient separation between Fe and V/Ti is achieved.
keywords: low grade vanadium-bearing titanomagnetite concentrates direct reduction metallization ratio separation
文章编号: 中图分类号: 文献标志码:
基金项目:国家自然科学基金资助项目(51374191,21506233),中国科学院科技服务网络计划(STS计划)项目(KFJ-SW-STS-148)
| 作者 | 单位 | |
| 白云 | 昆明理工大学冶金与能源工程学院 | baiyun@ipe.ac.cn |
| 陈德胜 | 中国科学院过程工程研究所 | |
| 马文会 | 昆明理工大学冶金与能源工程学院 | |
| 王丽娜 | 中国科学院过程工程研究所 | |
| 赵宏欣 | 中国科学院过程工程研究所 | |
| 甄玉兰 | 中国科学院过程工程研究所 | |
| 于宏东 | 中国科学院过程工程研究所 | |
| 齐涛* | 中国科学院过程工程研究所 | tqgreen@ipe.ac.cn |
| Author Name | Affiliation | |
| BAI Yun | Kunming University of Science and Technology | baiyun@ipe.ac.cn |
| CHEN De-sheng | ||
| MA Wen-hui | ||
| WANG Li-na | ||
| ZHAO Hong-xin | ||
| ZHEN Yu-lan | ||
| YU Hong-dong | ||
| QI Tao | tqgreen@ipe.ac.cn |
引用文本:
白云,陈德胜,马文会,王丽娜,赵宏欣,甄玉兰,于宏东,齐涛.直接还原处理低品位钒钛磁铁精矿[J].有色金属(冶炼部分),2017(9):48-53.
BAI Yun,CHEN De-sheng,MA Wen-hui,WANG Li-na,ZHAO Hong-xin,ZHEN Yu-lan,YU Hong-dong,QI Tao.Treatment of Low Grade Vanadium-Bearing Titanomagnetite Concentrates by Direct Reduction[J].Nonferrous Metals (Extractive Metallurgy),2017(9):48-53.
白云,陈德胜,马文会,王丽娜,赵宏欣,甄玉兰,于宏东,齐涛.直接还原处理低品位钒钛磁铁精矿[J].有色金属(冶炼部分),2017(9):48-53.
BAI Yun,CHEN De-sheng,MA Wen-hui,WANG Li-na,ZHAO Hong-xin,ZHEN Yu-lan,YU Hong-dong,QI Tao.Treatment of Low Grade Vanadium-Bearing Titanomagnetite Concentrates by Direct Reduction[J].Nonferrous Metals (Extractive Metallurgy),2017(9):48-53.

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