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投稿时间:2015-09-23 修订日期:2015-09-25 录用日期:2015-09-28 网络发布日期:2016-02-23
投稿时间:2015-09-23 修订日期:2015-09-25 录用日期:2015-09-28 网络发布日期:2016-02-23
中文摘要: 以等离子熔炼失效汽车催化剂得到的含铂、钯和铑的铁合金富集物为原料,研究了液固比、浸出温度、浸出时间和氧化剂用量对铁合金中铂、钯和铑浸出率的影响。结果表明,最佳浸出条件为:盐酸浓度6 mol/L、搅拌速度250 r/min时、液固比10︰1、浸出温度80 ℃、浸出时间2 h、氧化剂氯酸钠用量为1︰1,铂、钯和铑的浸出率分别为57.29%、62.12%和25.35%。
Abstract:Ferroalloy enrichment with platinum, palladium and rhodium from plasma melting of spent auto catalysts was applied as raw material. The effects of ratio of liquid to solid, leaching temperature, leaching time, and dosage of oxidant on leaching rates of Pt, Pd, and Rh from ferroalloy were investigated. The results show that leaching rate of Pt, Pd, and Rh is 57.29%, 62.12% and 25.35% respectively under the optimum conditions including concentration of hydrochloric acid of 6 mol/L, stirring speed of 250 r/min, ratio of liquid to solid of 10︰1, leaching temperature of 80 ℃, leaching time of 2 h, and dosage of oxidant sodium chlorate of 1︰1.
keywords: spent automobile exhaust catalysts plasma melting method resource regeneration PGMs concentrate
文章编号: 中图分类号: 文献标志码:
基金项目:云南省科技厅省院省校科技合作项目(2013IB020)
| 作者 | 单位 | |
| 吴喜龙 | 贵研资源(易门)有限公司 | wuxilongvip@sina.com |
| 贺小塘 | 贵研资源易门有限公司 | |
| 李红梅* | 贵研资源易门有限公司 | lhmhyq@126.com |
| 赵金成 | 贵研资源易门有限公司 | |
| 施秋杰 | 贵研资源易门有限公司 | |
| 汤永松 | 贵研资源易门有限公司 | |
| 李勇 | 贵研资源易门有限公司 | |
| 王欢 | 贵研资源易门有限公司 | |
| 赵雨 | 贵研资源易门有限公司 | |
| 雷霆 | 昆明冶金高等专科学校 |
| Author Name | Affiliation | |
| Wu xilong | recoverry | wuxilongvip@sina.com |
| he xiaotang | ||
| Li hongmei | lhmhyq@126.com | |
| zhao jincheng | ||
| SHI Qiu-jie | ||
| TANG Yong-song | ||
| li yong | ||
| wang huan | ||
| zhao yu | ||
| LEI Ting |
引用文本:
吴喜龙,贺小塘,李红梅,赵金成,施秋杰,汤永松,李勇,王欢,赵雨,雷霆.含铂钯铑的铁合金富集物溶解试验研究[J].有色金属(冶炼部分),2016(3):52-54.
Wu xilong,he xiaotang,Li hongmei,zhao jincheng,SHI Qiu-jie,TANG Yong-song,li yong,wang huan,zhao yu,LEI Ting.Dissolution Research of Platinum, Palladium and Rhodium Enriched Ferroalloy[J].Nonferrous Metals (Extractive Metallurgy),2016(3):52-54.
吴喜龙,贺小塘,李红梅,赵金成,施秋杰,汤永松,李勇,王欢,赵雨,雷霆.含铂钯铑的铁合金富集物溶解试验研究[J].有色金属(冶炼部分),2016(3):52-54.
Wu xilong,he xiaotang,Li hongmei,zhao jincheng,SHI Qiu-jie,TANG Yong-song,li yong,wang huan,zhao yu,LEI Ting.Dissolution Research of Platinum, Palladium and Rhodium Enriched Ferroalloy[J].Nonferrous Metals (Extractive Metallurgy),2016(3):52-54.

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